https://www.popsci.com/science/article/2011-01/chinese-invent-new-method-producing-healthier-light-water/ With New Method, China Can Mass-Produce Light Water
For Its Citizens' Thirst water with hardly any D2O — or light
water — can boost the immune system and benefit plant and animal
health, according to several studies. In one study from 2003,
plant photosynthesis increased with the use of light water. A
study involving mice
blasted with ionizing radiation showed a dramatic
difference in survival between mice that drank light water and
mice that drank regular water. It is even used as a cancer
treatment for humans: In 2008, researchers reported that light
water noticeably lengthened
the lifespan of terminal cancer patients...
Scientists in China are reporting development of a less
expensive, more eco-friendly method for making
deuterium-depleted drinking water, citing studies suggesting
that it may be a more healthful form of water. Their report
appears in ACS' bi-weekly journal Industrial & Engineering
Chemistry Research.
Changgong Meng and Feng Huang note that natural water, widely
known as H2O, actually is a mixture of H2O and tiny amounts of
D2O -- about 150 parts per million (ppm), or a few drops of D2O
in every quart of water. Deuterium-depleted water usually
contains about 125 ppm. The "D" is deuterium, an isotope or
variant form of hydrogen often termed "heavy hydrogen." They
cite accumulating evidence that water with high levels of
deuterium may have adverse health effects on animals and plants,
while deuterium-depleted water may be useful in treatment of
certain diseases. Existing ways of removing deuterium from water
tend to be expensive, inefficient, or environmentally harmful.
They describe a new method that helps overcome these problems,
and could be the basis for the first industrial-scale production
of deuterium-depleted water. It involves a platinum catalyst
that quickly and efficiently removes deuterium from water using
a combination of cold and hot temperatures. In laboratory-scale
tests, the new technique reduced the amount of deuterium in
water from about 145 parts per million to 125 parts per million.
The resulting water is suitable for drinking, the scientists
say, and could be produced in large quantities at economical
cost.
http://pubs.acs.org/stoken/presspac/presspac/full/10.1021/ie101820f Ind. Eng. Chem. Res. 2011, 50, 1, 378-381, November 29,
2010 https://doi.org/10.1021/ie101820f https://pubs.acs.org/doi/full/10.1021/ie101820f Method for the Production of Deuterium-Depleted Potable
Water Feng Huang, Changgong Meng Abstract -- A study of the utilization of
dual-temperature catalytic exchange between water and hydrogen
for the production of deuterium-depleted water is presented. We
use a novel catalyst with excellent physical properties for the
hot tower of the isotopic exchange. The deuterium-depleted water
obtained from the experiment is in agreement with the
theoretical consideration on deuterium content at 80 °C when λ
is about 1.5. The deuterium-depleted water with 126.3 ppm D2O is
gained when λ is about 2 under 80 °C. This kind of water can be
used as ordinary drinking water and in cosmetic and hygiene
products.
CN105314597 -- Deuterium
depleted water preparation method Inventor: HUANG FENG Applicant: UNIV LIAONING SCI & TECH
2016-02-10
The invention discloses a deuterium depleted water preparation
method which overcomes the defects that an existing preparation
method is high in energy consumption and low in separation
coefficient and causes pollution. The method includes the steps
of selecting a reaction tower as a deuterium depleted water
preparation device, selecting a catalyst of a cold tower as the
Pt/SDB hydrophobic catalyst, selecting a catalyst of a hot tower
as the Pt/PTFE hydrophobic catalyst, filling a bed layer of the
cold tower and a bed layer of the hot tower with the hydrophobic
catalysts and hydrophilic filler, connecting the cold tower with
the hot tower in series with the hot tower on the upper side and
the cold tower on the lower side, selecting deionized water as
the raw material water and high-purity hydrogen as the raw
material gas, introducing the raw material water and the raw
material gas into the reaction tower, conducting a chemical
exchange reaction on the raw material water and the raw material
gas in the cold tower and the hot tower, and obtaining fluid
flowing out of the tower bottom of the hot tower as deuterium
depleted water subjected to primary exchange. The method is
simple in principle, process and device, large in disposal
amount, capable of saving energy, free of pollution, and
suitable for large-scale production of deuterium depleted water
beverages.
Technical field
The invention belongs to the technical field of hydrogen isotope
separation, especially a method for preparing ultra-light water.
Background technique
In the nuclear industry, deuterium and heavy water are both very
important industrial raw materials.
However, according to many research results, deuterium is
harmful to the survival and reproduction of living organisms.
When the protium atoms in the DNA helical structure are replaced
by deuterium, it will cause phase shift, breakage or replacement
of the helical structure, causing the ribonucleic acid
arrangement to be disordered or even mutated.
Once deuterium enters the living body, it is difficult to
metabolize and remove it. High levels of deuterium have adverse
effects on the genetics and metabolism of the human body. The
D<sub> 2 </sub>O content in natural water is about
150ppm, and living organisms have developed adaptability. If the
D<sub> 2 </sub>O content in water exceeds this
normal value, it will cause certain harm to living organisms.
Ultra-light water, also known as deuterium-depleted water (DDW),
is water with a D<sub> 2 </sub>O content of less
than 150 ppm.
The application of ultra-light water is mainly reflected in
three aspects: First, it can promote the growth of animals and
plants. When the water contains less deuterium, fish and
plankton are more likely to reproduce; soaking seeds or watering
with ultra-light water makes it easier for seeds to germinate
and grow. and improve crop yield and quality. Second, it can be
used as an auxiliary treatment for diseases such as cancer and
diabetes. Ultra-light water can inhibit the decomposition and
replication of tumor cells and reduce the number of tumor cells.
Clinical results show that as an auxiliary treatment, using
ultra-light water to replace the patient's daily drinking water
can significantly prolong the life of the disease. patient's
lifespan. Third, it is used in health care and anti-aging.
Ultra-light water has antioxidant effects. In the ultra-light
water environment, the activity of antioxidant enzymes in the
human brain and liver is significantly increased. According to
the different D<sub> 2 </sub>O content in the water,
ultra-light water has four specifications: 125ppm±5ppm,
105ppm±5ppm, 50ppm±5ppm, and 25ppm±5ppm. Ultra-light water with
a D<sub> 2 </sub>O content of less than 80ppm can be
used for medical treatment, and ultra-light water with a
D<sub> 2 </sub>O content of 100-125ppm can be used
for health drinks, etc.
The methods currently used to produce ultra-light water mainly
include electrolysis, distillation, electrolysis combined with
distillation and H<sub> 2 </sub>O-H<sub> 2
</sub>S method, etc.
The most commonly used method for producing drinking ultra-light
water is distillation, in which water distillation and
low-temperature liquid hydrogen distillation technologies have
been successfully applied. The water distillation method is
simple, safe and reliable, but it has a small separation
coefficient, high energy consumption, high operating costs and
low recovery rate. Liquid hydrogen distillation has high
separation coefficient, low energy consumption, high production
capacity, short start-up time, and flexible design. However, it
has low operating temperature, extremely high thermal insulation
requirements, and high technical difficulties. The advantages of
the electrolysis method are high separation coefficient and
simple process, but the disadvantage is high power consumption.
H <sub> 2 </sub> O-H <sub> 2 </sub> S
exchange method is a chemical exchange method, which uses the
different distribution of isotopes among different chemical
components to achieve separation purposes. When two compounds of
the same element come into contact under certain conditions, the
distribution of different isotopes of the element in the
reactants before contact and the products after contact can
change. The H <sub> 2 </sub> O-H <sub> 2
</sub> S exchange reaction proceeds quickly and does not
require a catalyst, but H <sub> 2 </sub> S is toxic
and polluting.
The invention provides a method for preparing ultra-light water,
which overcomes the problems of high energy consumption, low
separation coefficient and pollution existing in the existing
preparation methods.
A method for preparing ultra-light water provided by the
invention includes the following steps:
a. The reaction tower is selected as a preparation device for
ultra-light water. The reaction tower is divided into two parts:
a cold tower and a hot tower. The catalyst for the cold tower is
Pt/SDB hydrophobic catalyst with a screening particle size of
1.5-3.0 mm. The catalyst for the hot tower is Pt/PTFE
hydrophobic catalyst, screening diameter is 2.0-3.0 mm;
b. Fill the beds of the cooling tower and the hot tower with
hydrophobic catalyst and hydrophilic filler. The volume ratio of
hydrophobic catalyst and hydrophilic filler is 1:1-1:6. One
layer of hydrophobic catalyst and one layer of hydrophilic
filler. A layer of hydrophobic catalyst and then a layer of
hydrophilic filler are sequentially packed;
c. The cooling tower and the hot tower are connected in series.
The upper part is the hot tower and the lower part is the
cooling tower. Before the reaction, the entire loop is purged
with nitrogen from bottom to top. The temperature of the cooling
tower is controlled at 20℃-20°C through the constant temperature
heating device outside the tower. 30℃, the temperature of the
hot tower is controlled at 80℃-130℃ through the constant
temperature heating device outside the tower.
d. Select deionized water as the raw water and high-purity
hydrogen as the raw gas. Feed the raw water and raw gas into the
reaction tower at a gas-liquid ratio of 1.5-2.5. The raw gas is
fed from the bottom of the cooling tower below. , the raw
material moisture is introduced from the top of the cooling
tower and the hot tower respectively. The gas discharged from
the top of the cooling tower is introduced into the bottom of
the hot tower. In the cooling tower and the hot tower, the raw
material water and the raw material gas undergo chemical
exchange reactions. , the liquid flowing out from the bottom of
the hot tower is ultra-light water after one exchange.
In the described step b, stainless steel reaction tubes or
quartz glass tubes are selected as the cooling tower and the hot
tower. The total filling height of the hydrophobic catalyst and
hydrophilic filler and the height-to-diameter ratio of the
reaction tower are 5-30.
In the described step d, the HDO content in deionized water is
290 ppm, which is obtained by deionizing natural drinking water.
The purity of high-purity hydrogen is 99.99%, and the HD content
is 284 ppm.
Compared with existing similar methods, the significant
beneficial effects of the present invention are reflected in:
The method of preparing ultra-light water using H <sub> 2
</sub> -H <sub> 2 </sub> O liquid phase
dual-temperature catalytic exchange has simple principles,
processes and equipment, large processing capacity, energy
saving, and no pollution.
Suitable for large-scale production of ultra-light water
drinks.=]
Detailed ways A method for preparing ultra-light water. The steps of the
method are as follows:
1. Select the reaction tower as an ultra-light water preparation
device. The reaction tower is divided into two parts: a cooling
tower and a hot tower. Select a Pt/SDB hydrophobic catalyst with
a particle size of 2 mm as the catalyst for the cold tower, and
select a Pt/PTFE hydrophobic catalyst with a particle size of 3
mm. Acts as a catalyst for thermal towers;
2. Select a quartz glass tube with an inner diameter of 20mm and
a length of 600mm as the cooling tower and the hot tower. Put
the Φ2mm θ-ring hydrophilic filler and the hydrophobic catalyst
into the cooling tower and the hot tower in layers at a volume
ratio of 3:1. A layer of hydrophobic catalyst, a layer of
hydrophilic filler, and then a layer of hydrophobic catalyst and
then a layer of hydrophilic filler are sequentially filled. The
total filling height is 400mm.
3. The cooling tower and the hot tower are connected in series,
with the hot tower at the top and the cooling tower at the
bottom. Before the reaction, the entire loop is purged with
nitrogen from bottom to top for 15 minutes to avoid the danger
of contact between hydrogen and oxygen. The nitrogen flow rate
is 30ml/min. The cooling tower temperature is controlled at 30°C
by a constant temperature heating device outside the tower, and
the hot tower temperature is controlled at 80°C by a constant
temperature heating device outside the tower.
4. Select deionized water with an HDO content of 290ppm as the
raw material water, select high-purity hydrogen with an HD
content of 284ppm as the raw material gas, and pass the raw
material water and raw gas into the reaction tower at a flow
ratio of 2 to the gas-liquid ratio. The raw gas will flow from
The bottom of the cooling tower located below is passed in. The
raw material moisture is introduced from the top of the cooling
tower and the hot tower respectively. The gas discharged from
the top of the cooling tower is passed into the bottom of the
hot tower. In the cooling tower and hot tower, The raw water and
raw gas undergo a chemical exchange reaction. The liquid flowing
out from the bottom of the hot tower is ultra-light water after
one exchange. After testing, the D<sub> 2 </sub>O
content of this ultra-light water is 126 ppm. https://www.ncbi.nlm.nih.gov/pubmed/18815148?dopt=Abstract DOI: 10.1177/1534735408322851 Integr Cancer Ther. 2008 Sep;7(3):172-81. A retrospective evaluation of the effects of deuterium
depleted water consumption on 4 patients with brain metastases
from lung cancer. Krempels K, et al.
CONCLUSIONS: DDW was administered as an oral anticancer agent in
addition to conventional therapy, and noticeably prolonged the
survival time of all 4 lung cancer patients with brain
metastasis. We suggest that DDW treatment, when integrated into
other forms of cancer treatment, might provide a new therapeutic
option.
http://www.russia-ic.com/news/show/2107/ http://www.vor.ru/science/science_rus.html#3 21.04.2006 Light Water Production Launched Russian Institute for Biological Medicine launched
production of light water, differing from ordinary water by
stimulating all human systems' activities through data-flow
level. Institute's vice-president claims such developments are
unique and cannot be found anywhere else in the world.
Natural light water is found in mountain rivers and melting
glaciers. Scientists designed rectifying columns for water
fractional distillation and derived water free from its heavy
components.
Light water normalizes any pathology found in an organism. It
also improves body resistance to harmful effects of physical,
chemical and biological origin. Clinical trials revealed light
water's ability to dissolve higher concentrations of various
substances and to penetrate membranes easier than ordinary
water. Light water showed anti-inflammatory effect and
eliminated tissue puffiness.
Recently developed "Langway" water is already available at the
US market. Tests proved its potential to refine cell metabolic
processes through accumulating energy inside a cell. Light water
is highly recommended for skin regeneration stimulation.
"Langway" tones the skin, reduces its greasiness, narrows skin
pores, slows ageing and helps skin to resist negative
environmental impact. Light water also regulates excretion of
toxins, salts of heavy metals, cellular debris and infectious
germs. Another positive aspect is that such water lowers blood
sugar and cholesterol, thus it can be recommended for patients,
suffering from diabetes, atherosclerosis, obesity and
hypertension.
Russian scientists developed and began to produce “live water” –
light water that removes harmful substances from body and
produces rejuvenating effect. “ “Langway-IBMED-50” purifies and
removes toxic products from body, salts of heavy metals and
other harmful substances”, - informed “Interfax” Chief Medical
Doctor - Director of the Institute of Biological Medicine
(IBMED), Academician Y. Bloshansky. According to him, natural
water is one of the factors of our body’s imperceptible
poisoning. “It contains heavy isotopes of hydrogen (deuterium)
and oxygen in quantities that considerably slow energy processes
in cells, harm body’s vitality and damage genic apparatus.” It
is caused by its dissociation with terrestrial organisms due to
space origin.
“Light water that has been purified of heavy isotopes acts on
all body cells and results in a healthy glow and skin”, said Y.
Bloshansky.
The academician is sure that usage of light water with low
contents of deuterium can prolong life of every organism both
unicellular and multicellular one.
For the first time mountain freshness for your skin! Unique
properties of light cosmetic water "Langway-IBMED" – keep your
youth!Unique properties of light cosmetic water "Langway-IBMED"
keep your youth!
• can be applied to all skin types, even for hypersensitive skin
- Light water contains nothing which can cause an allergic
reaction
• can be applied on make up for daily skin moisture
• stimulates processes of skin cells natural renewal, slows
ageing
• renews skin moisture
• increases skin tonus
• reduces inflammation
• reduces the adverse affects of heating systems, conditioners,
computers
• has a soothing action in case of sun burns
Clinical tests showed that light cosmetic water "Langway-IBMED"
intensifies epithelization, increases skin moisture, has
anti-inflammatory action, removes edemas.Clinical tests showed
that light cosmetic water "Langway-IBMED" intensifies
epithelization, increases skin moisture, has anti-inflammatory
action, removes edemas. Light cosmetic water "Langway-IBMED"
tones up, cleanses skin and increases the effect of cosmetic
products.Light cosmetic water "Langway-IBMED" tones up, cleanses
skin and increases the effect of cosmetic products. Solubility
of different substances in light water is higher than in
traditional water.Solubility of different substances in light
water is higher than in traditional water. Light water
"Langway-IBMED" has lower viscosity than usual water that allows
it to penetrate through cellular membranes.Light water
"Langway-IBMED" has lower viscosity than usual water that allows
it to penetrate through cellular membranes. Application of these
properties can significantly increase effectiveness of active
components of the "Celletelle" cosmetic products in complex face
skin care by application of different creams in combination with
light water.Application of these properties can significantly
increase effectiveness of active components of the "Celletelle"
cosmetic products in complex face skin care by application of
different creams in combination with light water. Clinical tests
in Cosmetology Clinic "Institute of Beauty" (Moscow) showed high
effectiveness of light water.Clinical tests in Cosmetology
Clinic Institute of Beauty "(Moscow) showed high effectiveness
of light water...
Additionally, for complex body rejuvenation it is recommended to
drink superlight biologicaly active medicinal water
"Langway-IBMED-50". Additionally, for complex body rejuvenation
it is recommended to drink superlight biologicaly active
medicinal water "Langway-IBMED-50." Medicinal water
“Langway-IBMED-50” has a wide spectrum of biological activity,
in particular: increases immunity, has detoxifying action,
stimulates regeneration of cells and tissues.Medicinal water
"Langway-IBMED-50" has a wide spectrum of biological activity,
in particular : increases immunity, has detoxifying action,
stimulates regeneration of cells and tissues.
Restores youth and longevity!
• stimulates processes of self-renewal – regeneration of cells
and tissues
• improves water metabolism, removes disorders of fatty
metabolism, obesity and edemas
• purifies and removes metabolism products from the body,
removes salt of heavy metals, toxins and other harmful
substances;
• increases speed of water-lipidic metabolism and normalizes
metabolism processes in body;
• increases body energy resources increases and immunity,
prevents inflammation, in particular on skin surface – pustules,
acne, eczema, etc.
• has rejuvenating effect
• increases viability and quality of sex cells
• prevents body from accumulation and affection of radionuclids;
inhibits growth of several tumors, including – lungs carcinoma,
uterine sarcoma, cervical carcinoma
• normalizes condition of hair, nails, skin turgor and provides
healthy glow
• reduces sugar content, triglycerides and cholesterol in blood;
is applied in case of diabetes 1 and 2, atherosclerosis, obesity
• stabilizes cellular membranes and vessels permeability
• has hypotensive action; is applied in case of arterial
hypertension and neurocirculatory dystonia
• reduces alcohol withdrawal syndrome
• with longer use – improves sleep, memory, mental and physical
activity
• is recommended in case of diets, during fasting days
Tests of light water ( in vitro) at the A.Tests of light water
(in vitro) at the A. P.P. Hertsen Moscow Scientific Research
Oncological Institute and the Scientific-Research Institute of
Carcerogenesis of N.N.Hertsen Moscow Scientific Research
Oncological Institute and the Scientific-Research Institute of
Carcerogenesis of N. Blochin and the Russian Oncological
Scientific Centre in cooperation with State Scientific Centre of
the Russian Federation "Institute of medical-biological
problems" confirmed inhibiting action of light water on
multiplication of tumorous cells and growth of tumors.Blochin
and the Russian Oncological Scientific Centre in cooperation
with State Scientific Centre of the Russian Federation
"Institute of medical-biological problems "confirmed inhibiting
action of light on water multiplication of tumorous cells and
growth of tumors.
Clinical tests in N.N.Clinical tests in N. Blochin Scientific
Centre showed that application of light water in complex
treatment of patients suffering from breast cancer removes
consequences of toxics (vomiting, pain, hair shedding) caused by
chemotherapy.Blochin Scientific Centre showed that application
of light water in complex treatment of patients suffering from
breast cancer removes consequences of toxics (vomiting, pain,
hair shedding) caused by chemotherapy.
Tests carried out in laboratories of Scientific Centre of
Children Health of the Russian Academy of Medical Sciences
showed that application of light water significantly increases (
by 30%) energy resources in cells as well as level of cells
protection from penetration of different toxins.Tests carried
out in laboratories of Scientific Centre of Children Health of
the Russian Academy of Medical Sciences showed that application
of light water increases significantly (by 30%) energy resources
in cells as well as level of protection cells from penetration
of different toxins.
The effect of light drinking water on patients with different
metabolic disorders (arterial hypertension, obesity,
carbohydrate metabolism disorders, dislipidemia, diabetes 1 and
2) was examined by the Endocrinology Department of the Russian
Scientific Centre of Renewing Medicine and Balneology of the
Ministry of Health of the Russian Federation.The effect of light
drinking water on patients with different metabolic disorders
(arterial hypertension, obesity, carbohalrate metabolism
disorders, dislipidemia, diabetes 1 and 2) was examined by the
Endocrinology Department of the Russian Scientific Centre of
Renewing Medicine and Balneology of the Ministry of Health of
the Russian Federation. After the course of application of light
water, patients with increased level of beta —
lipoproteins and coefficient of atherogeneity showed marked
reduction of indices.After the course of application of light
water, patients with increased level of beta - lipoproteins and
coefficient of atherogeneity showed marked reduction of indices.
In this group beta — lipoproteins index reduced by 52% and
coefficient of atherogeneity – by 113%.In this group
beta-lipoproteins index reduced by 52% and coefficient of
atherogeneity-by 113%. In the control group reduction of indices
made 43% and 35%.In the control group reduction of indices made
43% and 35%. Results of tests confirm that light water has
effective hypoglycemic, hypolipidemic and hypotensive action on
the body of patients with different metabolic disorders, it
improves metabolism processes and increases body
immunity.Results of tests confirm that light water has effective
hypoglycemic, hypolipidemic and hypotensive action on the body
of patients with different metabolic disorders, it improves
metabolism processes and increases body immunity.
On the basis of results of these tests light drinking water is
recommended by Russian Scientific Centre of Renewing Medicine
and Balneology of the Ministry of Health of the Russian
Federation in complex treatment of diabetes 2 and different
metabolic disorders as well as in program of weight
correction.On the basis of results of these tests light drinking
water is recommended by Russian Scientific Centre of Renewing
Medicine Balneology and of the Ministry of Health of the Russian
Federation in complex treatment of diabetes 2 and different
metabolic disorders as well as in program of weight correction.
Daily dose – 1 liter.Daily dose-1 litem judges. First glass of
water on empty stomach in the morning.First glass of water on
empty stomach in the morning. Optimal course – from 2 months of
application.Optimal course-from two months of application.
It is not recommended to apply superlight biologicaly active
medicinal water "Langway-IBMED-50" later than 2 hours before
sleep since it has expressed tonic action.It is not recommended
to apply superlight biologicaly active medicinal water
"Langway-IBMED-50" later than two hours before sleep since it
has expressed tonic action.
Constant application of medicinal water can significantly
prolong life of any body.Constant application of medicinal water
can significantly prolong life of any body.
For convenience of application in cosmetology light water is
produced as aerosol.For convenience of application in
cosmetology light water is produced as aerosol. Due to its
unique structure and properties this water stimulates skin
regeneration, reduces inflammations, slows skin ageing and has
rejuvenating and moistening action.Due to its unique structure
and properties this water stimulates skin regeneration, reduces
inflammations, slows skin ageing and has rejuvenating and
moistening action.
Certificate of registration of the Ministry of Health of the
Russian Federation N 77.99.15.6.U.918.2.05. dated
03.02.2005.dated February 3, 2005.
Term of storage 12 months
LIGHT
WATER PATENTS
UA66109 -- METHOD FOR THE PREPARATION OF PURIFIED
BIOLOGICALLY ACTIVE HEALING WATER AT A LOW CONTENT OF HEAVY
HYDROGEN ISOTOPES AND"VIN-KOLO", A PLANT FOR REALIZING THE
SAME
Abstract --- A method for the preparation of biologically active
healing water at a low content of heavy hydrogen isotopes
involves operations of preliminary purification of original
water from hazardous and poisonous substances, water cooling and
subsequent removing heavy hydrogen isotopes - deuterium and
radioactive tritium from water in the water flow by an
optionally solid condensation of these heavy isotopes in two
stages. Upon obtaining the required ice thickness the
crystallization process is stopped and simultaneously heavy
oxygen isotopes Ä17 and Ä18 is removed. Thereafter the light
water with a low content of heavy hydrogen and oxygen isotopes
is collected, thawing and pouring of condensate is performed,
obtained water is activated by an optimization of mineral
composition and structure thereof. Before removal of heavy
hydrogen isotopes from water the original water is overcooled to
the temperature of -0.5...-10c with an intensive agitation
thereof. A plant for realizing the method contains a unit of
preliminary cooling the original water, condensation apparatus,
apparatus of overcooling below 0 0c and intensive agitation of
the original water. The condensation apparatus is made in the
form of closed vertical disposed hollow water conduit of -like
form, which has heat-exchangers installed, which are connected
to the refrigerating fluid and heat carrier sources, and
straight flow pump with flow regulator. The upper branch of the
water conduit is connected to the unit of preliminary cooling
original water and to the apparatus of preliminary purification
and decontamination of water, and the lower one is connected to
the apparatus for optimization of mineral composition and
structure of water. The heat exchangers are made in the form of
tubular multi-row spiral having space between the coils filled
with heat-conducting material and noble minerals. The apparatus
of overcooling and intensive agitation of the original water
contains processing chamber of cylindrical form with conical
bottom and cover. The system of water condensation is disposed
under cover, and above the cover the apparatus for reciprocal
rotation of heavy water isotopes is disposed which is made in
the form of tubular multi-row spiral.
US2006016681 -- Apparatus and Method for Separating Tritated
and Heavy Water from Light Water via a Conical Configuration
[ PDF ] Abstract --- An system for separating tritiated
water from common water, using gravity and the freezing point
of tritiated water to cause tritiated water to freeze along
the inside of a conically-shaped collection chamber. The
common water and liquid tritiated water that pass out the
bottom of the conically-shaped collection chamber are pumped
back to the top of the conically-shaped collection chamber for
repeated runs until sufficient tritiated water has frozen to
the inside of the conically-shaped collection chamber. A water
wheel is positioned to assist in powering the pump that drives
water through repeated runs.
US6984327 -- System and Method for Separating Heavy Isotopes
of Hydrogen Oxide from Water [ PDF ] Abstract --- An apparatus and method for separating
heavy isotopes of hydrogen from contaminated water. The
apparatus includes a treatment chamber with an elongated hollow
core fiber (HCF) extending within the chamber. A reservoir holds
contaminated water mixed with beads formed of an exchange resin,
the mixture of contaminated water and beads forming a flowable
slurry. The slurry is continuously circulated through the hollow
core fiber and the reservoir preferably by a pulsating
peristaltic pump. The beads absorb a portion of the heavy
isotopes from the slurry by exchange with waters of hydration of
the beads while the hollow core fiber allows permeation of only
light water from said slurry outwardly through the HCF wall as a
permeate. CN101088920A -- Prepn process of no-deuterium water
The present invention
is distilling and layered fractioning technology to obtain
no-deuterium water with high energy, high purity, no heavy water
and no superheavy water. The no-deuterium water is used as water
for injection, industrial super purified water, drinking water,
domestic water, agricultural water, health water and water for
scientific research, and may be used in compounding
germanium-rich water, selenium-rich water, zinc-rich water,
iron-rich water, SOD water, etc.
CN110104859A -- Water treatment method for removing deuterium
oxide The present invention relates to a kind of high-energy,
high-purity, deuterium-free water that does not contain heavy
water and super-heavy water obtained by layered fractionation
technology.
Ordinary drinking water or natural mineral water, even the best
distilled water, contains heavy water deuterium
(D<sub>2</sub>O), super heavy water tritium
(T<sub>2</sub>O), other minerals, inorganic salts,
and metal ions. The state of water is in the form of
macromolecular clusters. . The present invention adopts the most
advanced layered fractionation technology to obtain high-purity
deuterium-free water that does not contain heavy water and
super-heavy water.
Deuterium-free water is pure water (H<sub>2</sub>O).
The content of pure water reaches 99.9999%, the content of heavy
water is less than 1PPm, and it does not contain any other
minerals, inorganic salts, bacteria, pigments, heat sources,
metal ions, and other heavy metal ions. , pesticides,
fertilizers, heavy water deuterium (D<sub>2</sub>O),
super heavy water tritium (T<sub>2</sub>O),
disinfectants, detergents and other charged substances.
Deuterium-free water is powerful ultrapure, ultraclear, and
ultrapure water with short-chain molecules that are uncharged
and have no molecular groups.
Deuterium-free water has high energy, high metabolic power,
dissolving power, cleaning power, diffusion power, penetrating
power, emulsifying power and oxygen capacity (extra oxygen),
achieving unprecedented nutrition and energy, and promoting the
absorption of nutritional substances. Metabolism and the
elimination of toxic and harmful substances from the body
improve the quality of life.
Characteristics of deuterium-free water: freezes at 0℃, ice
crystals are hexagonal, vaporizes at 100℃, has the smallest
volume and maximum density at 4℃, which is
1g/cm<sup>3</sup>, the conductivity is less than 2
units (s/cm), and it is colorless , tasteless, transparent,
neutral and suitable in taste.
Deuterium-free water can be used for medical injections,
industrial ultrapure water, drinking water, domestic water,
agricultural water, health care water, scientific research
water, and can be used to prepare germanium-rich water,
selenium-rich water, zinc-rich water, iron-rich water, SOD
water, various vitamin waters, fruit drinks, magnetized water,
ionized water, etc.
Specific Implementation Process for preparing deuterium-free
water: distillation - layered fractionation - secondary
pressurized fractionation - fractional extraction - high-speed
plasma crushing - high-intensity magnetization - high-voltage
electric field rectification - rearrangement - inspection -
storage - ultrasonic disinfection - packaging
-Inspection-Sealing-Packaging into boxes-Make
anti-counterfeiting marks-Sealing the boxes-Affixing labels and
numbers to the boxes-Putting into storage. CN1085191A -- Process for preparing deuterium-free water
Deuterium-free water is
produced from ordinary water by steam fractionation and does not
contain other matter and deuteroxide. It is mainly used for
drinking, immersion of seeds and irrigation to increase yield of
crops, speed up growth of animal and fowls, and raise egg-laying
rate...
CN102205992 -- Preparation method of deuterium-free water
and dedicated packed tower thereof
The invention provides
a preparation method of deuterium-free water and a dedicated
packed tower thereof. The packed tower comprises a packed tower
shell, wherein the packed tower shell is internally provided
with a plurality of screens which are up and down ranked and in
seal fit with the packed tower shell; gaps are reserved among
the screens; the inner cavity of the packed tower shell is
divided into a plurality of small chambers by the screens; and
each screen is formed by overlapping multiple layers of silk
screens. The preparation method comprises the following steps:
introducing water vapor from the bottom of the packed tower to
the cavity of the packed tower; successively enabling the water
vapor to pass through the screens so as to lift to the top of
the packed tower from the bottom of the packed tower, so that
deuterium-free water vapor is obtained; and cooling the
deuterium-free water vapor so as to obtain the deuterium-free
water. The preparation method in the invention has the
advantages of large deuterium-free water extraction amount, high
purity and stable quality; and the obtained deuterium-free water
has a huge development potential, a wide market and a practical
application value, can be applied to the fields of medicinal
injection liquids, industrial ultrapure water, drinking water,
domestic water, agricultural water, health water and scientific
water, and can be used for preparing Ge-enriched water,
selenium-enriched water, zinc-enriched water, iron-enriched
water, superoxide dismutase (SOD) water, various vitamin water,
fruit juice, magnetized water, ionized water and the like.
Background technique Deuterium-free water is pure water
(H<sub>2</sub>O). The content of pure water reaches
99.9999% and does not contain any other minerals, inorganic
salts, bacteria, pigments, heat sources, metal ions, other heavy
metal ions, pesticides, chemical fertilizers, heavy water
deuterium (D<sub>2</sub>O ), super heavy water
tritium (T<sub>2</sub>O), disinfectants, cleaning
agents and other charged substances.
Deuterium-free water is powerful ultra-pure, ultra-clear and
ultra-pure water with short-chain molecules that are uncharged
and have no molecular groups. Characteristics of deuterium-free
water: freezes at 0℃, ice crystals are hexagonal, vaporizes at
100℃, has the smallest volume and maximum density at 4℃,
1g/cm<sup>3</sup>, conductivity is less than 2 units
(s/cm), colorless , tasteless, transparent, neutral and suitable
in taste. Deuterium-free water has high energy, high metabolic
power, dissolving power, cleaning power, diffusion power,
penetration power, emulsifying power and oxygen capacity (extra
oxygen), achieving unprecedented nutrition and energy, and
promoting the absorption of nutritional substances. Metabolism
and the elimination of toxic and harmful substances from the
body improve the quality of life. Deuterium-free water can be
used for medical injections, industrial ultrapure water,
drinking water, domestic water, agricultural water, health care
water, scientific research water, and can be used to prepare
germanium-rich water, selenium-rich water, zinc-rich water,
iron-rich water, SOD water, various vitamin waters, fruit
drinks, magnetized water, ionized water, etc.
At present, many foreign countries have conducted research on
low-deuterium water.
In 1992, Hungarian SOMLYAI, JANCSO and JAKLI studied a method
for preparing low-deuterium water. Ordinary water containing 150
ppm deuterium was boiled under reduced pressure and a 30-50
plate packed column. The water vapor obtained at the top
contained deuterium. The content is 15-30ppm. In 2006, Romania's
INSTNAT CERC-DEZVOLTARE TEHNOLOGII CRIO studied a method for
preparing low-deuterium water, which was obtained by
continuously introducing pure water into an isotope distillation
tower with a height-to-diameter ratio of 45:1. The superhydrogen
water obtained by this method has a deuterium content of
20-30ppm and can be used for food. The above preparation method
is complicated to operate, requires high equipment, and the
deuterium-depleted water obtained has a high deuterium content.
Therefore, there is an urgent need for a deuterium-free water
preparation method that is simple to operate.
Contents of the invention The object of the present invention is to provide a
preparation method of deuterium-free water and its special
packed tower.
The invention provides a packing tower, which includes a packing
tower shell. There are several mesh plates arranged up and down
in the packing tower shell and sealingly matched with the side
walls of the packing tower shell. One of the mesh plates is
There is a spacing between them, and the mesh plate divides the
inner cavity of the packing tower into several small chambers;
each mesh plate is formed by superimposing several layers of
wire mesh.
In the above-mentioned packed tower, the mesh plates may be
arranged in parallel.
In the above-mentioned packed tower, the spacing between the
mesh plates may be 50 cm to 70 cm.
In the above packed tower, the inner diameter of the packed
tower may be 5 meters; the height of the packed tower may be 50
meters.
In the above-mentioned packed tower, the number of mesh plates
can be 50 to 70; each mesh plate can be composed of 10 to 20
layers of wire mesh.
In the above-mentioned packed tower, the thickness of each mesh
plate may be 8 cm to 12 cm; the mesh density of the mesh may be
150 mesh to 300 mesh.
In the above-mentioned packed tower, the mesh plate, wire mesh
and packed tower can all be made of stainless steel.
The present invention also provides a method for preparing
deuterium-free water, which involves introducing water vapor
from the bottom of the packed tower into the cavity of the
packed tower; the water vapor passes through the packed tower in
sequence from the bottom of the packed tower. The mesh plate
rises to the top of the packed tower to obtain deuterium-free
water vapor, and the deuterium-free water vapor is obtained by
cooling the deuterium-free water vapor.
In the above method, the pressure in the packed tower can be
8MPa-10MPa, specifically 8MPa or 10MPa; the water vapor can be
generated by heating.
In the above method, the mass content of deuterium in the water
vapor may be
1.5×10<sup>-4</sup>-2.0×10<sup>-4</sup>.
In the above method, the yield of deuterium-free water can reach
30%-50%.
The purity of the deuterium-free water prepared by the method
provided by the invention is as high as 99.9999%. After
ultrasonic disinfection, it can be used to prepare medical
injections, industrial ultrapure water, etc.; the preparation
method provided by the invention extracts a large amount of
deuterium-free water with high purity. High, stable quality;
deuterium-free water has huge development potential, broad
market, and practical application value. It can be used for
medical injections, industrial ultrapure water, drinking water,
domestic water, agricultural water, health care water and
scientific research water. wait.
Description of the drawings Figure 1 is a schematic structural diagram of a packed tower
according to Embodiment 1 of the present invention.
In the figure, the marks are as follows: 1. Packing tower shell,
2. Screen plate.
Detailed ways The experimental methods used in the following examples are
conventional methods unless otherwise specified.
Materials, reagents, etc. used in the following examples can all
be obtained from commercial sources unless otherwise specified.
The deuterium content in deuterium-free water in the following
embodiments 2 and 3 of the present invention is detected by an
isotope detector. The isotope detector is a Beta-RAM4 isotope
detector produced by IN/US Company of the United States; other
microbial indicators in deuterium-free water , The impurity
content is tested according to ("Bottled Drinking Purified
Water" GB 17323-1998) and ("Industrial Deionized Distilled
Water" GB 6682-2007).
Example 1, packed tower The inner diameter of the packing tower provided by the
invention is 5 meters, the height is 50 meters, and the material
is stainless steel; the packing tower includes a packing tower
shell 1, and the packing tower shell 1 is provided with 60 upper
and lower blocks (not shown in the figure). The mesh plates 2
are arranged and sealingly matched with the side wall of the
packing tower shell. The mesh plates 2 are arranged in parallel.
The spacing between the mesh plates 2 is 60 cm. The inner cavity
of the packing tower shell is divided into 61 Small chambers
with equal volumes (not shown in the figure); each screen plate
2 is made of 15 layers of 200-mesh wire mesh (not shown in the
figure), and the thickness of each screen plate 2 is 9 cm.
In the above-mentioned packing tower, the number of mesh plates
2 can be adjusted within 50-70 pieces as needed; the thickness
of each mesh plate 2 can be adjusted within 8 cm-10 cm as
needed; the spacing between mesh plates 2 It can be adjusted
within 50 cm - 70 cm as needed; the number of layers of wire
mesh included in each screen panel 2 can be adjusted within 10
layers - 20 layers as needed; the mesh density of the wire mesh
can be adjusted between 150 mesh and 150 mesh as needed. Adjust
within 300 mesh.
Example 2. Preparation of deuterium-free water Drinking water is heated to generate water vapor. The mass
content of deuterium in the water vapor is
1.5×10<sup>-4</sup>. The water vapor is introduced
from the bottom of the packed tower of Example 1 into the packed
tower. The pressure in the packed tower is set to 8MPa. The
steam rises from the bottom of the packed tower through 60 mesh
plates 2 to the top of the packed tower to obtain deuterium-free
water vapor, which is then led out through stainless steel pipes
and cooled to obtain deuterium-free water with a purity of
99.9999% and no other microbial impurities. It was detected that
the yield of deuterium-free water was 30%; waste water and
distilled water were collected from the bottom and middle bottom
of the packed tower respectively.
Example 3. Preparation of deuterium-free water Drinking water is heated to generate water vapor. The mass
content of deuterium in the water vapor is
2.0×10<sup>-4</sup>. The water vapor is introduced
from the bottom of the packed tower of Example 1 into the packed
tower. The pressure in the packed tower is set to 10MPa. The
water vapor rises from the bottom of the packed tower through 60
mesh plates to the top of the packed tower to obtain
deuterium-free water vapor, which is then led out through
stainless steel pipes. After cooling, deuterium-free water is
obtained. Its purity is 99.9999%, and other microbial impurities
are not present. It was detected that the yield of
deuterium-free water was 50%; waste water and distilled water
were collected from the bottom and middle bottom of the packed
tower respectively. CN105036078 -- Deuterium-depleted water preparation
system and implementation method The
invention discloses a deuterium-depleted water preparation
system. The deuterium-depleted water preparation system
comprises a raw material water tank, a first liquid metering
pump and a second liquid metering pump which are both connected
with the raw material water tank, a first vaporizer connected
with the first liquid metering pump, a second vaporizer
connected with the second liquid metering pump, a first fixed
bed reactor which is connected with the first vaporizer and
filled with iron powder, a third fixed bed reactor which is
simultaneously connected with the second vaporizer and the first
fixed bed reactor and filled with porous foam nickel, a first
condenser connected with the third fixed bed reactor, a first
water storage tank connected with the first condenser and a poor
deuterium hydrogen circulation processing device connected with
the first condenser. The deuterium-depleted water preparation
system is ingenious in structural design and convenient to
control, the preparation cost of deuterium-depleted water can be
significantly lowered, so that the deuterium-depleted water can
be well applied and popularized in the bio-medical treatment
field, and therefore the higher practical value is achieved.
CN110015791 -- Special device for removing heavy
deuterium oxide
Background technique
Modern science has proven that deuterium is harmful to the
survival, development and reproduction of living
organisms. Because deuterium replaces hydrogen atoms, it
can generate additional stress in the helical structure of
DNA, causing phase shifts, breaks, and replacements of the
double helix, causing the ribonucleic acid arrangement to
be disordered and even rearranged. Synthesis, mutations
occur, which have adverse effects on the human body's
genetics, metabolism, and enzyme systems. As a result,
during the process of gene replication, the probability of
cell defects continues to increase, increasing the
possibility of tumor cells.
Low-deuterium water refers to water with a deuterium
content of less than 150 ppm. Tests by Hungarian scientist
Gabor Somlyai and Kanagawa University in Japan and others
have proven that low-deuterium water has a variety of
biological effects that are beneficial to the human body:
1) Activating human cells: When the body is heavy The
overall reduction of hydrogen concentration can
significantly promote enzyme reactions, improve basal
metabolism, and help activate body cells; 2) Enhance human
immunity: it can increase NK cell activity values, improve
the body's immune disorders, thereby enhancing human
immune function; 3) Prevention Cancer health care
function: By depriving cancer cells of the heavy hydrogen
environment required for their value-adding, increasing
blood oxygen content and oxygen absorption, activating the
vitality of human tissue cells, improving cellular
immunity, and restoring the overall functions of cell
tissues, organs and systems, it can reduce the risk of
cancer. Tumor indicator value, inhibiting the
proliferation of deteriorated cells and cancer cells.
At present, the main methods for large-scale production of
low-deuterium water include distillation method and
water/hydrogen dual-temperature exchange method.
The distillation method is based on the different
volatilities of hydrogen or two components of
hydrogen-containing compounds (such as H <sub> 2
</sub> O and D <sub> 2 </sub> O), and
isotope separation occurs during the coexistence of gas
and liquid phases.
Distillation is carried out in a distillation tower
equipped with several trays or packings. The liquid phase
and the gas phase flow countercurrently in the tower.
During the rising process of the steam, H<sub> 2
</sub>O is gradually enriched due to its high
volatility; while in the liquid phase, H<sub> 2
</sub>O is gradually enriched. During the process of
overflowing to the bottom of the tower, D<sub> 2
</sub>O is gradually enriched due to its low
volatility.
The steam is condensed at the top of the tower and
refluxes into the tower. There is a still at the bottom of
the tower to evaporate part of the liquid to provide an
upward airflow.
The advantage of the water distillation method is that it
does not require the use of catalysts or chemical
reagents, and the production process is simple and mature;
however, because the separation coefficient is very small,
about 1.03 to 1.06, many separation stages need to be
connected in series, so the equipment is tall and complex,
and the construction investment is large.
In addition, due to the need for repeated condensation and
vaporization, a very large amount of water needs to be
processed during the production process, resulting in high
energy consumption and high operating costs.
The water/hydrogen dual-temperature exchange method is
based on the unequal probability equilibrium distribution
characteristics of hydrogen isotopes among the reacting
molecules. The separation coefficient α of the exchange
reaction changes with temperature. The higher the
temperature, the closer α tends to 1.
In the cold tower, deuterium is enriched from the gas
phase to the liquid phase. In the hot tower, α decreases
as the temperature increases, so the opposite mass
transfer process occurs, that is, deuterium is transferred
from the liquid phase to the gas phase. In this way, the
low-temperature main tower, that is, the cold tower, is
used for enrichment, and the high-temperature auxiliary
tower, that is, the hot tower, is used to achieve phase
conversion, so that the water is depleted to form
low-deuterium water. However, the industrial application
of the water/hydrogen dual-temperature exchange method has
the following problems: on the one hand, the cooling tower
must use expensive platinum-based hydrophobic catalysts as
fillers, and the system construction cost is high; on the
other hand, the exchange reaction of water/hydrogen
isotopes It includes two continuous processes of liquid
phase catalytic exchange and vapor phase catalytic
exchange, and the control of parameters such as
temperature and flow rate is relatively complex.
In summary, due to the limitations of existing methods,
the cost of preparing low-deuterium water is generally
high and difficult to produce on a large scale. This also
severely limits the promotion and application of
low-deuterium water in the biomedical field.
Contents of the invention
The purpose of the present invention is to provide a
low-deuterium water preparation system and its
implementation method, which mainly solves the problem of
high processing costs in the existing low-deuterium water
preparation methods.
In order to achieve the above objects, the technical
solutions adopted by the present invention are as follows:
A low deuterium water preparation system includes a raw
material water tank, a first liquid metering pump and a
second liquid metering pump with input ends connected to
the output end of the raw material water tank, and a first
vaporizer with an input end connected to the output end of
the first liquid metering pump. , the second vaporizer
whose input end is connected to the output end of the
second liquid metering pump, the input end is connected to
the output end of the first vaporizer and the first fixed
bed reactor filled with iron powder with a particle size
<100nm, and the input end is connected to the first
fixed bed reactor at the same time. The respective output
ends of the two vaporizers and the first fixed bed reactor
are connected and the third fixed bed reactor filled with
porous nickel foam, the input end is connected to the
first condenser which is connected to the output end of
the third fixed bed reactor, and A first water storage
tank connected to the output end of the first condenser,
and a deuterium-depleted hydrogen circulation treatment
device connected to the output end of the first condenser
for collecting deuterium-depleted product water.
Specifically, the deuterium-depleted hydrogen circulation
treatment device includes a hydrogen storage tank
connected to the output end of the first condenser, a gas
circulation pump whose input end is connected to the
hydrogen storage tank, and the input end is connected to
the output end of the gas circulation pump. and a second
fixed-bed reactor filled with ferroferric oxide powder
with a particle size <100 nm, a second condenser with
an input end connected to the output end of the second
fixed-bed reactor, and a second condenser connected to the
output end of the second condenser of the second water
storage tank.
Further, the first vaporizer is simultaneously connected
to the first fixed bed reactor and the second fixed bed
reactor through a first three-way valve; the third fixed
bed reactor is simultaneously connected to the first fixed
bed reactor through a second three-way valve. The bed
reactor is connected to the second fixed bed reactor.
Furthermore, the gas circulation pump is simultaneously
connected to the first fixed bed reactor and the second
fixed bed reactor through a third three-way valve; the
second condenser is simultaneously connected to the first
fixed bed reactor through a fourth three-way valve. The
reactor is connected to a second fixed bed reactor.
Preferably, the first three-way valve, the second
three-way valve, the third three-way valve and the fourth
three-way valve are all two-position three-way valves.
Furthermore, all connected parts and components are
connected through pipes, and the outer walls of all pipes
are wrapped with fiberglass heating tapes.
In order to achieve thermal insulation of the pipeline,
the outer layer of the fiberglass heating tape is also
wrapped with an aluminum silicate fiber cotton layer.
According to the above system structure, the present
invention also provides a method for implementing the low
deuterium water preparation system, which includes the
following steps:
(1) Switch the first three-way valve and the second
three-way valve to connect the first fixed bed reactor to
the first vaporizer and the third fixed bed reactor at the
same time. Switch the third three-way valve to connect the
gas circulation pump to the third fixed bed reactor. The
two fixed bed reactors are connected; the fourth three-way
valve is switched to connect the second fixed bed reactor
with the second condenser;
(2) Turn on the first liquid metering pump and the second
liquid metering pump respectively, divide the water stored
in the raw water tank into two pumps, and enter the first
vaporizer and the second vaporizer respectively to form
water vapor;
(3) The water vapor in the second vaporizer enters the
third fixed-bed reactor; at the same time, the water vapor
in the first vaporizer enters the first fixed-bed reactor
and undergoes an oxidation-reduction reaction with iron
powder to generate hydrogen and tetrahydrogen. Oxide
ferric iron, and then hydrogen enters the third fixed bed
reactor;
(4) Hydrogen and water vapor undergo a hydrogen-water
catalytic exchange reaction in the third fixed-bed
reactor, and deuterium is transferred from hydrogen to
water vapor to obtain deuterium-poor hydrogen and
deuterium-rich water vapor;
(5) Deuterium-poor hydrogen and deuterium-rich water vapor
enter the first condenser at the same time. Deuterium-rich
water vapor is condensed into liquid water and collected
into the first water storage tank under the action of
gravity; at the same time, deuterium-poor hydrogen is
condensed into liquid water. Send it to the hydrogen
storage tank
(6) Turn on the gas circulation pump and pump the
deuterium-depleted hydrogen in the hydrogen storage tank
into the second fixed-bed reactor to undergo an
oxidation-reduction reaction with ferric oxide to generate
deuterium-depleted water vapor and metallic iron;
deuterium-depleted water vapor It enters the second
condenser and is condensed into deuterium-depleted product
water, which is collected under gravity into the second
water storage tank for storage.
Further, if both the first fixed bed reactor and the
second fixed bed reactor fail, perform the following
steps:
(a) Switch the first three-way valve and the second
three-way valve to connect the second fixed bed reactor to
the first vaporizer and the third fixed bed reactor at the
same time. Switch the third three-way valve to connect the
gas circulation pump to the third fixed bed reactor. A
fixed bed reactor is connected; the fourth three-way valve
is switched to connect the first fixed bed reactor with
the second condenser;
(b) Turn on the first liquid metering pump and the second
liquid metering pump respectively, pump the water stored
in the raw water tank into two channels, and enter the
first vaporizer and the second vaporizer respectively to
form water vapor;
(c) The water vapor in the second vaporizer enters the
third fixed-bed reactor; at the same time, the water vapor
in the first vaporizer enters the second fixed-bed reactor
and undergoes an oxidation-reduction reaction with iron
powder to generate hydrogen and tetrahydrogen. Oxide
ferric iron, and then hydrogen enters the third fixed bed
reactor;
(d) Perform steps (4) to (6), and switch the second fixed
bed reactor in step (6) to the first fixed bed reactor.
Compared with the prior art, the present invention has the
following beneficial effects:
(1) In the present invention, a vaporizer and a fixed bed
reactor are set up, and iron powder, ferric oxide and
porous nickel foam are respectively loaded into the
corresponding fixed bed reactors, and then a condenser and
a deuterium-depleted hydrogen circulation treatment device
are set up. , thereby realizing the oxidation, reduction
and hydrogen-water catalytic exchange reactions of
hydrogen, combined with the physical changes of
condensation and the circulation treatment of hydrogen, to
prepare low-deuterium water with a very low deuterium
concentration.
After testing, the low-deuterium water preparation method
designed in the present invention has a large separation
coefficient (≥2.0). Therefore, compared with the
traditional distillation method, the volume of the
equipment of the present invention is significantly
reduced, and the construction cost and operating energy
consumption are reduced. significantly reduce.
(2) Compared with equipment that uses water/hydrogen
dual-temperature exchange method to prepare low-deuterium
water, the present invention does not require a cooling
tower for liquid-phase catalytic exchange reaction, so it
has a simple structure and a small footprint; and, the
present invention The thermal tower filler can meet the
requirements by using low-priced porous nickel foam and
does not require the use of expensive platinum-based
precious metal catalysts. Therefore, the construction cost
and operating energy consumption of the system are also
significantly reduced.
(3) The present invention sets up a first fixed bed
reactor and a second fixed bed reactor in parallel, and
makes full use of the reversible reaction characteristics
of the filler iron filled in them after cooperating with
the switching of multiple three-way valves. One of the two
fixed-bed reactors is always in the iron reduction state
and the other is in the iron oxidation state. This not
only cleverly realizes the continuous operation of the
entire system, but also the filler can be used repeatedly
without replacement, which greatly improves the efficiency
of low-deuterium water. The preparation efficiency is
high, and it creates very favorable conditions for quickly
obtaining low-deuterium water with lower deuterium
concentration.
The present invention can obtain low-deuterium water with
a deuterium concentration of ≤100 ppm at a relatively
lower cost, which also provides a good foundation for the
promotion and application of low-deuterium water in the
biomedical field.
(4) The implementation of the design of the present
invention only requires natural water as raw material, and
does not require auxiliary media such as hydrogen to
obtain the required low-deuterium water. Therefore, the
system operation is simpler. At the same time, each
reaction is carried out in a series of fixed beds. It is
carried out in a closed-circuit system connected to the
reactor, so the safety of the system is also higher
(5) In the present invention, all pipes used for
connecting components are wrapped with fiberglass heating
tapes, and the fiberglass heating tapes are also wrapped
with a layer of aluminum silicate fiber cotton, which can
realize heating and insulation of the pipelines, making
the pipelines The temperature everywhere is kept above
100°C to avoid premature condensation of water vapor into
liquid water during the preparation of low-deuterium
water.
Description of the drawings
Figure 1 is a schematic diagram of the system structure of
the present invention.
Figure 2 is a schematic flow chart of the present
invention.
Figure 3 is another flow diagram of the present invention.
Among them, the names of parts corresponding to reference
marks are:
1-raw material water tank, 2-first liquid metering pump,
3-second liquid metering pump, 4-first vaporizer, 5-second
vaporizer, 6-first three-way valve, 7-first fixed bed
reactor, 8-The second fixed bed reactor, 9-The second
three-way valve, 10-The third fixed bed reactor, 11-The
first condenser, 12-The first water storage tank,
13-Hydrogen storage tank, 14-Gas Circulation pump,
15-third three-way valve, 16-fourth three-way valve,
17-second condenser, 18-second water storage tank.
Detailed ways
The present invention will be further described below in
conjunction with the accompanying drawings and examples.
Implementations of the present invention include, but are
not limited to, the following examples.
Example
As shown in Figure 1, the present invention provides a
brand new system for preparing low deuterium water, which
includes a raw water tank 1, a first liquid metering pump
2, a second liquid metering pump 3, a first vaporizer 4,
and a second vaporizer 5 , the first fixed bed reactor 7,
the third fixed bed reactor 10, the first condenser 11 and
the deuterium-depleted hydrogen circulation treatment
device.
The raw material water tank 1 is used to load liquid
water, and has two water outlet pipelines, which are
respectively connected to the first liquid metering pump 2
and the second liquid metering pump 3. In this embodiment,
both liquid metering pumps use The diaphragm pump controls
the flow of two-way liquid water through stroke and
frequency adjustment. The stroke is used for rough
adjustment of flow, and the frequency adjustment uses a
frequency converter for fine adjustment of flow.
The first vaporizer 4 is connected to the first liquid
metering pump 2, and the second vaporizer 5 is connected
to the second liquid metering pump 3. The vaporizer is
used to vaporize liquid water into water vapor. In this
embodiment, both vaporizers use Stainless steel spiral
coiled tube, the coiled tube is placed in the heating
furnace, the liquid water enters the spiral tube at high
temperature, and is heated and vaporized directly into
water vapor.
The temperature-control thermocouple probe of the heating
furnace is placed at the outlet of the vaporizer. By
adjusting the heating power, it can ensure that the steam
temperature at the outlet of the vaporizer is ≥200°C, and
there is no liquid water retention, which facilitates
accurate control of steam flow.
The first fixed bed reactor 7 is filled with ultra-fine
iron powder with a particle size of <100nm, which is
used to react with water vapor to generate hydrogen and
ferric oxide, and then ferric oxide can react with
hydrogen to produce iron and water.
The input end of the third fixed bed reactor 10 is
connected to the respective output ends of the second
vaporizer 5 and the first fixed bed reactor 7 at the same
time, and is filled with porous nickel foam as a filler
for hydrogen and water vapor. A catalytic exchange
reaction occurs. In this embodiment, the reaction of the
third fixed bed reactor 10 is 200°C. Calculated according
to the exchange reaction equilibrium constant, the
water-hydrogen exchange equilibrium constant is about 2 at
200°C, and the deuterium in the hydrogen will move to the
water. It is enriched in the steam to obtain
deuterium-poor hydrogen and deuterium-rich water vapor.
The input end of the first condenser 11 is connected to
the output end of the third fixed bed reactor 10 for
condensing deuterium-rich water vapor into liquid water,
and then collecting it and connecting it to the output end
of the first condenser 11 in the first water storage tank
12.
The first condenser 11 in this embodiment is a
conventional vertical shell-and-tube heat exchanger, with
cooling water flowing on the shell side and water vapor
flowing on the tube side. The heat exchange area is
determined based on the gas flow rate and temperature
difference.
The gas outlet temperature can be lowered to room
temperature through parameter settings, most of the water
vapor will be condensed into liquid water, and the water
content in the remaining hydrogen is <2%.
The deuterium-depleted hydrogen recycling treatment device
is used to collect deuterium-depleted hydrogen and process
it to obtain deuterium-depleted water products.
Specifically, the deuterium-depleted hydrogen circulation
treatment device includes a hydrogen storage tank 13
connected to the output end of the first condenser 11, a
gas circulation pump 14 connected to the input end of the
hydrogen storage tank 13, and a gas circulation pump 14
with an input end connected to the gas circulation pump
14. The output end is connected to a second fixed bed
reactor 8 filled with Fe3O4 with a particle size of
<100 nm, the input end is connected to the second
condenser 17 of the second fixed bed reactor 8, and the
second condenser 17 is connected to the output end of the
second fixed bed reactor 8, and the The output end of the
second condenser 17 is connected to the second water
storage tank 18 .
The first vaporizer 4 is simultaneously connected to the
first fixed bed reactor 7 and the second fixed bed reactor
8 through the first three-way valve 6; the third fixed bed
reactor 10 is simultaneously connected through the second
three-way valve 9 Connected to the first fixed bed reactor
7 and the second fixed bed reactor 8 .
The gas circulation pump 14 is simultaneously connected to
the first fixed bed reactor 7 and the second fixed bed
reactor 8 through the third three-way valve 9; the second
condenser 17 is simultaneously connected through the
fourth three-way valve 16 Connected to the first fixed bed
reactor 7 and the second fixed bed reactor 8 .
The first three-way valve 6, the second three-way valve 9,
the third three-way valve 15 and the fourth three-way
valve 16 used above are all two-position three-way valves,
and the valves are switched manually or pneumatically.
The second condenser 17 is also a water-cooled vertical
shell-and-tube heat exchanger.
The hydrogen storage tank 13 is a flexible airbag, its
volume can change with the gas storage capacity, and the
air pressure in the container is maintained at normal
pressure.
The gas circulation pump 14 is a bellows pump, which can
not only meet the air tightness requirements of hydrogen,
but also ensure that the sealing material will not pollute
the gas.
As shown in Figure 2, using the above system, the process
of collecting deuterium-depleted water products in this
embodiment is introduced below.
Take the preparation of low-deuterium water with a
deuterium concentration of 100 ppm as an example.
First, use natural water as raw water and put it into the
raw water tank 1. Then switch the first three-way valve 6
and the second three-way valve 9 so that the first
fixed-bed reactor 7 can communicate with the first
vaporizer 4 and the third vaporizer at the same time.
Fixed bed 10 is connected; switch the third three-way
valve 15 to connect the gas circulation pump 14 to the
second fixed bed reactor 8; switch the fourth three-way
valve 16 to connect the second fixed bed reactor 7 to the
second condenser 17 Connected.
Then the first liquid metering pump 2 and the second
liquid metering pump 3 are turned on respectively, and the
raw water stored in the raw water tank is divided into two
pumps (A and B in Figure 2), and enters the first
vaporizer respectively. 4 and the second vaporizer 5,
water vapor is formed.
The water vapor from route B enters the third fixed bed
reactor 10, while the water vapor from route A enters the
first fixed bed reactor 7 and undergoes an oxidation
reaction with iron powder to generate hydrogen and ferric
oxide, and then hydrogen Then it enters the third fixed
bed reactor 10 to be mixed with water steam.
The mixed hydrogen and water vapor, catalyzed by the
porous nickel foam filler, undergo a hydrogen-water
catalytic exchange reaction, and deuterium is transferred
from hydrogen to water vapor to obtain deuterium-poor
hydrogen and deuterium-rich water vapor.
The obtained deuterium-poor hydrogen and deuterium-rich
water vapor enter the first condenser 11 at the same time,
and the deuterium-rich water vapor is condensed into
liquid water and collected into the first water storage
tank 12 under the action of gravity; at the same time, the
deuterium-poor hydrogen is sent to the hydrogen storage
tank 13.
The gas circulation pump 14 is turned on, and the
deuterium-depleted hydrogen in the hydrogen storage tank
13 is pumped into the second fixed-bed reactor 8 to
undergo a reduction reaction with ferroferric oxide to
generate deuterium-depleted water vapor and metallic iron.
Immediately afterwards, the deuterium-depleted water vapor
enters the second condenser 17 and is condensed into
deuterium-depleted product water, and is collected into
the second water storage tank 18 under the action of
gravity.
After the above processing, the second water storage tank
18 can collect the deuterium-depleted water product with
low deuterium concentration.
To obtain low deuterium water with a lower deuterium
concentration, the above cycle process can also be used;
for example, after obtaining a first-level
deuterium-depleted water product with a deuterium
concentration of 100 ppm, it is necessary to obtain a
second-level deuterium-depleted water product with a
deuterium concentration of 69 ppm. , then the first-level
deuterium-depleted water product can be used as raw
material and sent to the water tank 1, and then the above
treatment process can be continued to cycle.
It should be noted that in the above system, the connected
components are all connected through pipelines, and the
outer walls of all pipelines are wrapped with fiberglass
heating tapes to provide heat to the pipelines.
In addition, the outer layer of the pipe is also wrapped
with an aluminum silicate fiber cotton layer, which serves
as a thermal insulation material to keep the temperature
throughout the pipe above 100°C to prevent water vapor
from condensing into liquid water.
As shown in Figure 3, when the first and second fixed bed
reactors fail, the first fixed bed reactor 7 changes to
the oxidation state, that is, ferric oxide, and the second
fixed bed reactor 8 changes to the reduction state, that
is, metal iron.
Use the following steps to continue working:
First, use natural water as raw water and put it into the
raw water tank 1. Then switch the first three-way valve 6
and the second three-way valve 9 so that the second
fixed-bed reactor 7 can communicate with the first
vaporizer 4 and the third vaporizer at the same time. The
fixed bed 10 is connected; switch the third three-way
valve 15 to connect the gas circulation pump 14 to the
first fixed bed reactor 8; switch the fourth three-way
valve 16 to connect the first fixed bed reactor 7 to the
second condenser 17 Connected.
Then the first liquid metering pump 2 and the second
liquid metering pump 3 are turned on respectively, and the
raw water stored in the raw water tank is divided into two
pumps (A and B in Figure 2), and enters the first
vaporizer respectively. 4 and the second vaporizer 5,
water vapor is formed.
The water vapor from route B enters the third fixed bed
reactor 10, while the water vapor from route A enters the
second fixed bed reactor 7 and undergoes an oxidation
reaction with iron powder to generate hydrogen and ferric
oxide, and then hydrogen Then it enters the third fixed
bed reactor 10 to be mixed with water steam.
The mixed hydrogen and water vapor, catalyzed by the
porous nickel foam filler, undergo a hydrogen-water
catalytic exchange reaction, and deuterium is transferred
from hydrogen to water vapor to obtain deuterium-poor
hydrogen and deuterium-rich water vapor.
The obtained deuterium-poor hydrogen and deuterium-rich
water vapor enter the first condenser 11 at the same time,
and the deuterium-rich water vapor is condensed into
liquid water and collected into the first water storage
tank 12 under the action of gravity; at the same time, the
deuterium-poor hydrogen is sent to the hydrogen storage
tank 13.
The gas circulation pump 14 is turned on, and the
deuterium-depleted hydrogen in the hydrogen storage tank
13 is pumped into the first fixed bed reactor 8 to undergo
a reduction reaction with ferric tetraoxide to generate
deuterium-depleted water vapor and metallic iron.
Immediately afterwards, the deuterium-depleted water vapor
enters the second condenser 17 and is condensed into
deuterium-depleted product water, and is collected into
the second water storage tank 18 under the action of
gravity.
In order to obtain low-deuterium water with a lower
deuterium concentration, the deuterium-depleted product
water collected in the second water storage tank 18 can be
used as raw material and sent to the raw material water
tank 1 in the same manner as in Embodiment 1, and then the
above-mentioned treatment process can be continued to
circulate.
In the present invention, two fixed-bed reactors can be
arranged in parallel and then placed in the same electric
furnace. In this way, the heat released by the oxidation
reaction can be used to compensate for the heat absorption
of the reduction reaction. This heat The comprehensive
utilization can effectively reduce the heating energy
consumption of electric furnaces.
The low-deuterium water preparation system designed by the
present invention significantly reduces the preparation
cost of low-deuterium water compared with the traditional
distillation method and water/hydrogen dual-temperature
catalytic exchange method, and is conducive to the use of
low-deuterium water in the biomedical field. Promote
applications.
Therefore, the present invention breaks through the
limitations of the existing technology, achieves major
innovation, and conforms to the trend of scientific and
technological development.
Compared with the prior art, the present invention has
outstanding substantive features and significant progress.
CN109455669 -- System and method
for preparing deuterium-depleted water and deuterium-rich
water by separating natural water
The invention discloses a system for
preparing deuterium-depleted water and deuterium-rich water by
separating natural water. A core of the system is provided
with a closed loop, a plurality of separation columns are
sequentially connected in an end-to-end manner to form the
closed loop, the system further comprises a raw material water
storage tank, a deuterium-rich water storage tank, a
deuterium-depleted water storage tank, a metering pump, a
carburetor, pipelines and valves, and the pipelines and the
valves are connected with the devices. According to the
system, separation is implementedby the aid of moving bed
simulation principles, raw material water vapor circularly
moves in the closed loop formed by the separation columns
through sequentially heating and cooling of the
separationcolumns and control of a one-way valve, a constantly
increased deuterium concentration gradient is acquired along
with increase of cycle number, the deuterium-rich water is
extracted from the top ofthe separation column at the near end
of a heating loop, and the deuterium-depleted water is
extracted from the bottom of the separation column at the far
end of the heating loop after certain times of heating and
cooling circulation of the separation columns are implemented.
The system is simple in structure, convenient to control,
smaller in device size and lower in construction cost, fillers
are low in cost, and the natural water can be directly
separated by the aid of a semi-continuous mode to prepare the
deuterium-depleted water and the deuterium-rich water.
Technical field
The invention relates to the technical field of water
treatment, and specifically relates to a system and method for
separating natural water to prepare deuterium-poor water and
deuterium-rich water.
Background technique
Low-deuterium water refers to water with a deuterium content
of less than 150 ppm. Tests by Hungarian scientist Gabor
Somlyai and Japan's Kanagawa University Kanbanbo and others
have proven that low-deuterium water has a variety of
biological effects that are beneficial to the human body:
activating human cells and enhancing human immunity. ,
anti-cancer and health care functions, etc.
Low-deuterium water is currently an important auxiliary
product for cancer treatment in the world. Some countries in
the world that have the conditions are committed to the
research and development of low-deuterium water. For example,
Japan, the United States, Romania, etc. have put products on
the market. In the field of cancer treatment Already applied
in advance.
On the other hand, heavy water (D<sub>2</sub>O)
with a high deuterium content also has extremely important
uses.
Heavy water can be used as a moderator in nuclear reactors,
reducing the speed of neutrons and controlling the nuclear
fission process; heavy water is a valuable tracer material in
studying chemical and physiological changes, such as measuring
the metabolism of water in plants and animals. process; in
addition, if the research object of NMR analysis is hydrogen,
heavy water is also used as the solvent.
The raw materials for the production of low-deuterium water
and heavy water are natural water with abundant resources and
low price. The current methods for producing low-deuterium
water and heavy water mainly include high-tower stratified
distillation and water/hydrogen dual-temperature exchange
method.
The distillation method is based on the different volatilities
of various components of natural water (such as
H<sub>2</sub>O, HDO, and a very small amount of
D<sub>2</sub>O), and hydrogen isotope separation
can occur during the coexistence of gas and liquid phases.
During the rising process of steam, H<sub>2</sub>O
is gradually enriched at the top of the column due to its high
volatility. During the process of the liquid overflowing to
the bottom of the column step by step, HDO (including a very
small amount of D<sub>2</sub>O) is gradually
enriched at the bottom of the column due to its low
volatility. Enrichment. The advantage of the water
distillation method is that it does not require the use of
catalysts or chemical reagents, and the production process is
simple and mature; however, because the separation coefficient
is very small, about 1.03 to 1.06, many separation stages need
to be connected in series, so the equipment is tall and
complex, and the construction investment is large; in addition
, due to the need for repeated condensation and vaporization,
a very large amount of water needs to be processed during the
production process, which consumes a lot of energy and has
high operating costs. The water/hydrogen dual-temperature
exchange method is based on the unequal probability
equilibrium distribution characteristics of hydrogen isotopes
among the reacting molecules. The separation coefficient α of
the exchange reaction changes with the temperature. The higher
the temperature, the more α tends to 1. In the cold tower,
deuterium is enriched from the gas phase to the liquid phase.
In the hot tower, α decreases as the temperature increases, so
the opposite mass transfer process occurs, that is, deuterium
is transferred from the liquid phase to the gas phase. In this
way, the low-temperature main tower, that is, the cold tower,
is used for enrichment, and the high-temperature auxiliary
tower, that is, the hot tower, is used to achieve phase
conversion, so that the water is depleted to form
low-deuterium water. However, the industrial application of
the water/hydrogen dual-temperature exchange method has the
following problems: on the one hand, the cooling tower must
use expensive platinum-based hydrophobic catalysts as fillers,
and the system construction cost is high; on the other hand,
the exchange reaction of water/hydrogen isotopes It includes
two continuous processes of liquid phase catalytic exchange
and vapor phase catalytic exchange, and the control of
parameters such as temperature and flow rate is relatively
complex.
Japanese research shows that silica gel, activated alumina and
5A molecular sieve are used as fillers to separate tritiated
water (HTO) and light water (H<sub>2</sub>O) in
fixed bed carrier gas flow mode.
However, current water separation research using the
above-mentioned inorganic fillers only uses a small-scale
fixed bed carrier gas purge mode. After bed penetration, there
is a large amount of water remaining in the molecular sieve
filler, which requires complex regeneration before it can be
reused, and the separation efficiency is low. , has no
practical application value.
Contents of the invention
Based on the above problems, the present invention proposes a
system for separating natural water to prepare deuterium-poor
water and deuterium-rich water. Compared with the traditional
distillation method and double-temperature exchange method,
this system has a simple structure, cheap fillers, convenient
control, and larger equipment scale. It is small and has lower
construction cost. It can use semi-continuous mode to directly
separate natural water to produce deuterium-poor water and
deuterium-rich water.
In order to achieve the above objects, the technical solutions
adopted by the present invention are as follows:
A system for separating natural water to prepare
deuterium-poor water and deuterium-rich water, including a
sealed electric heating box, a separation component arranged
inside the electric heating box, and a raw water storage tank,
a deuterium-rich water storage tank and a deuterium-depleted
water storage tank arranged outside the electric heating box.
Water storage tank; the separation component includes
separation columns No. 1 to No. Water pipe, the raw material
water inlet pipe is installed through the electric heating
box, and the raw material water inlet pipe outside the
electric heating box is equipped with a metering pump, and the
raw material water inlet pipe inside the electric heating box
is equipped with a vaporizer, and the upper end of the No. 1
to No. n-1 separation columns They are respectively connected
to the raw material water inlet pipes through their
corresponding No. 1 to No. n-1 feed valves; the deuterium-rich
water storage tank is provided with a deuterium-rich water
pipe, and the deuterium-rich water pipe is installed through
the electric heating box, and the 1 The upper end of the No. n
separation column is connected to the deuterium-rich water
pipe through a deuterium-rich water valve; the
deuterium-depleted water storage tank is provided with a
deuterium-depleted water pipe, and the deuterium-depleted
water pipe is installed through the electric heating box; the
lower end of the No. n separation column passes through the
deuterium-depleted water The valve is connected to the
deuterium-depleted water pipe.
Specifically, it also includes a vacuum pump arranged outside
the electric heating box. The vacuum pump is provided with a
vacuum tube. The vacuum tube is arranged through the electric
heating box. The lower ends of the No. 1 to No. n separation
columns pass through the corresponding No. 1 to No. n columns
respectively. The vacuum valve is connected to the vacuum pipe
pipeline.
Specifically, the electric heating box is a phenolic foam
board box, with a dry-burning electric heating rod installed
at the bottom of the electric heating box, and the temperature
inside the box is not lower than 100°C.
As a preferred option, the separation column uses molecular
sieve as filler.
As a preferred solution, the separation column is a Φ50-Φ250
stainless steel pipe, with a stainless steel head welded on
the end face, and connected to a Φ10-Φ20 stainless steel
bellows, and the bellows are connected by ferrules or welding.
As a preferred solution, the outer wall of the separation
column is wrapped with a stainless steel mica thin-walled
annular heating ring so that its rated operating temperature
is not less than 500°C.
As a preferred solution, the metering pump is a diaphragm
pump.
Further, the vaporizer is a stainless steel spiral coil tube.
The coil tube is placed in the heating furnace. The liquid
water enters the spiral tube at a high temperature and is
heated and vaporized directly into steam without any retention
of liquid water.
Furthermore, the vacuum pump is a combination of a water ring
pump and a rotary vane pump. The front stage is a water ring
pump, and the rear stage is a rotary vane pump with a gas
ballast valve.
The invention also provides a method for preparing
deuterium-poor water and deuterium-rich water using the above
system. This method can directly separate natural water in a
semi-continuous mode to produce deuterium-poor water and
deuterium-rich water. The operation is simple and the
separation efficiency is high. The separation effect is good.
The method for preparing deuterium-poor water and
deuterium-rich water using the above system includes the
following steps:
S1: Set the internal temperature of the electric heating box
to above 100°C, turn on the heating ring outside the
separation column to raise the temperature of each separation
column to above 300°C, vacuum to remove the residual water
vapor in the separation column, and then lower it to 100°C;
S2: The natural water in the raw water storage tank is
extracted through the metering pump, and then converted into
water vapor through the vaporizer, and then enters the No. 1
to No. n-1 separation columns;
S3: Turn on the heating ring to raise the temperature of the
No. 1 separation column to above 300°C. The water vapor in the
No. 1 separation column desorbs and the pressure in the column
rises. When it exceeds the opening pressure of the one-way
valve, the water vapor moves backward into the No. 2 column.
This in turn causes the water vapor in column No. 2 to enter
column No. 3 through the one-way valve, and this process
occurs in subsequent separation columns. Finally, all the
water vapor in separation columns No. 1 to No. n-1 enters
separation columns No. 2 to No. n. The first rearrangement is
completed, and the deuterium concentration in the water vapor
gradually decreases along No. 2→N. When there is no
significant change in the pressure in the No. 1 separation
column, vacuum the residual water vapor in the No. 1 column to
regenerate it, and at the same time close the No. 1 column. J;
S4: When the temperature of column No. 1 drops to 100°C, turn
on the heating of column No. 2. The water vapor will desorb
and move backwards driven by the pressure difference. All the
water vapor will enter the separation columns No. 3 to No. n
and No. 1 to complete the second step. rearrangement; after
the desorption of No. 2 column is completed, perform the
regeneration of No. 2 column and the desorption of No. 3
column in the same way; the subsequent operations of the
separation column can be deduced in sequence; when the
desorption of the No. n separation column is completed, the
water vapor undergoes the nth After the second rearrangement,
the water vapor is again distributed in the separation columns
No. 1 to No. n-1, indicating that the system has completed a
cycle of separation;
S5: Connect the deuterium-rich water storage tank pipeline,
turn on the heating ring to heat the No. 1 separation column,
discharge the deuterium-rich water from the top of the No. 1
separation column and collect it; connect the deuterium-poor
water storage tank pipeline, heat the n-1 separation column
column, discharge deuterium-poor water from the bottom of the
column and collect it; then inject raw water from the middle
section of the separation loop to perform the next cycle of
separation operation.
Compared with the prior art, the present invention has the
following beneficial effects:
(1) The system of the present invention for separating natural
water to prepare deuterium-poor water and deuterium-rich water
adopts the simulated moving bed principle. Through the
sequential heating/cooling of the separation column and the
control of the one-way valve, the raw material water vapor
circulates in the closed loop formed by the separation column.
The deuterium concentration gradient is obtained by moving.
The deuterium concentration is the highest at the proximal end
of the heated desorption loop, while the deuterium
concentration gradually decreases at the far end, and the
deuterium concentration gradient continues to increase as the
number of adsorption/desorption times of the separation column
increases.
After the separation column undergoes a certain number of
heating and cooling cycles, the separation column at the
proximal end of the loop is heated to extract deuterium-rich
water from the top of the column; the separation column at the
far end of the loop is heated to extract deuterium-poor water
from the bottom of the column; then injection and extraction
are performed from the middle section of the loop equal
amounts of raw material water vapor for the next stage of
separation operation.
Compared with the traditional distillation method and
double-temperature exchange method, it has a simple structure,
cheap fillers, easy control, smaller equipment scale, and
lower construction costs. It can use semi-continuous mode to
directly separate natural water to produce deuterium-poor
water and Deuterium rich water.
(2) The separation method of the present invention is flexible
in operation and can easily obtain deuterium-poor water and
deuterium-rich water with different deuterium contents through
process control. The desired separation effect can be obtained
by adjusting the number of separation columns or the number of
cyclic separation operations. Adaptable.
(3) The present invention is based on simulated moving bed
technology. In the system of the present invention, the
adsorbent (i.e., the separation component) is fixed, and the
fluid (i.e., natural water vapor) is continuously flowed in
the separation loop through process parameter control,
producing a similar Based on the gas and solid phase
counterflow effect of a real moving bed, as time goes by, the
deuterium concentration gradient of the water vapor adsorption
zone in the solid phase molecular sieve continues to increase,
thereby achieving the separation of deuterium-poor water and
deuterium-rich water.
The system of the present invention not only has higher
production capacity and separation efficiency than the
traditional fixed bed, but also can avoid real moving bed
adsorbent wear, debris or dust clogging, or channeling between
solid particles.
(4) The present invention creatively applies simulated moving
bed technology to the separation of natural water. Through the
closed-loop separation system design, steam can continuously
circulate in the closed-loop separation loop. Under
temperature conditions above 100°C, H<sub>2</sub>O
and HDO ( As well as the difference in adsorption/desorption
performance of a very small amount of
D<sub>2</sub>O) on molecular sieves, it can
achieve one-step efficient separation using natural water as
the direct treatment object, and simultaneously obtain
deuterium-poor water and deuterium-rich water, which can
effectively reduce preparation costs and expand application
fields.
(5) The separation method of the present invention adopts
cumulative cycle separation operation. The hydrogen/deuterium
separation coefficient in natural water is significantly
larger than that of the distillation method. Compared with the
traditional distillation method, the equipment volume is
significantly reduced, and the construction cost and operating
energy consumption can be greatly reduced; compared with water
/Hydrogen dual-temperature exchange method, the filling
material is low-priced molecular sieves, does not require the
use of platinum-based precious metal catalysts, and has stable
long-term performance, thus greatly reducing system costs.
(6) The working medium of the separation method of the present
invention is only water vapor with a temperature of about
100°C. The separation operation is carried out in a closed
loop composed of a series of separation columns. There is no
need for auxiliary media such as hydrogen, so it is not only
easier to operate, but also flame-free. explosion and other
safety risks.
(7) Since the raw material is natural water, while
deuterium-poor water is produced, deuterium-rich water can
also be obtained as a raw material for heavy water production.
Therefore, the preparation cost of deuterium-poor water can be
greatly reduced, which will help promote the use of
deuterium-poor water in biology. Applications in the medical
field.
Description of the drawings
Figure 1 is a schematic structural diagram of the system of
the present invention.
Among them, the names corresponding to the reference signs
are:
1-separation column, 11-one-way valve, 2-vacuum pump,
21-vacuum tube, 22-vacuum valve, 3-raw water storage tank,
31-raw material water inlet pipe, 32-feed valve, 33-metering
pump, 34- Vaporizer, 4-deuterium-rich water storage tank,
41-deuterium-rich water pipe, 42-deuterium-rich water valve,
5-deuterium-poor water storage tank, 51-deuterium-poor water
pipe, 52-deuterium-poor water valve.
Detailed ways
The present invention will be further described below in
conjunction with the description of the drawings and examples.
The modes of the present invention include but are not limited
to the following examples. Example
The purpose of this embodiment is to provide a system for
separating natural water to prepare deuterium-poor water and
deuterium-rich water, which not only helps to solve the
current high cost problem of deuterium-poor water prepared by
distillation and double-temperature exchange methods, but also
can obtain deuterium-poor water at the same time.
Deuterium-enriched water is used as a raw material for heavy
water production.
A system for separating natural water to prepare
deuterium-poor water and deuterium-rich water. As shown in
Figure 1, the system includes a sealed electric heating box, a
separation component arranged inside the electric heating box,
and a raw water storage tank 3 arranged outside the electric
heating box. , deuterium-rich water storage tank 4,
deuterium-poor water storage tank 5 and vacuum pump.
The electric heating box is a phenolic foam board box, and a
dry-fired electric heating rod is installed at the bottom of
the electric heating box to make the temperature inside the
box above 100°C to ensure that water vapor will not condense
into liquid water.
Specifically, the core of the system is the separation
component. The separation component is a plurality of
separation columns (No. 1 to No. n, n≥2). The separation
columns are numbered (No. 1→No. 2→…→No. n→No. 1). A closed
loop is formed by connecting pipelines in sequence. The
pipelines between adjacent separation columns are also
equipped with one-way valves 11 for waterproof steam reflux.
The opening pressure difference of all one-way valves is
adjustable from 0.1MPa to 0.5MPa. When the pressure inside the
column Exceeding the set value can cause unidirectional flow
to the rear separation column.
The separation column uses molecular sieves as fillers, such
as 4A, 5A, carbon molecular sieves, etc. This is because
molecular sieve fillers not only still have a water absorption
rate of more than 15% above 100°C, but also have stable
properties and will not powder during the
adsorption/desorption process. chemical and can be used for a
long time; the separation column is a Φ50~Φ250 stainless steel
tube, with a stainless steel head welded on the end face,
connected to a Φ10~Φ20 stainless steel bellows, and the
bellows are connected by clamping or welding; and the outer
wall of the separation column is wrapped with stainless steel
mica thin Wall annular heating ring, long-term use temperature
can reach 500℃.
The raw material water storage tank 3 is provided with a raw
material water inlet pipe 31, which is provided through the
electric heating box, and a metering pump 33 is provided on
the raw material water inlet pipe 31 outside the electric
heating box, and a metering pump 33 is provided on the raw
material water inlet pipe inside the electric heating box.
There is a vaporizer 34, and the upper ends of the No. 1 to
No. n-1 separation columns are respectively connected to the
raw water inlet pipes through the corresponding No. 1 to No.
n-1 feed valves 32, and the raw water in the raw water storage
tank is extracted through a metering pump. Natural water is
converted into water vapor through the vaporizer and enters
the No. 1 to No. n-1 separation columns; the metering pump 33
is a diaphragm pump that can perform two-dimensional
adjustment of the output flow through stroke and frequency.
The stroke is used for rough adjustment of flow. The frequency
is used for fine adjustment of the flow rate; the vaporizer 34
is a stainless steel spiral coil tube, which is placed in the
heating furnace. The liquid water enters the spiral tube at
high temperature and is heated and vaporized directly into
steam. There is no liquid water retention, which is
convenient. Accurate control of steam flow.
The deuterium-rich water storage tank 4 is provided with a
deuterium-rich water pipe 41. The deuterium-rich water pipe is
installed through the electric heating box. The upper end of
the No. 1 separation column is connected to the deuterium-rich
water pipe through a deuterium-rich water valve 42;
The deuterium-depleted water storage tank 5 is provided with a
deuterium-depleted water pipe 51. The deuterium-depleted water
pipe is installed through the electric heating box. The lower
end of the n separation column is connected to the
deuterium-depleted water pipe through a deuterium-depleted
water valve 52.
The vacuum pump 2 is provided with a vacuum tube 21, which
runs through the electric heating box. The lower ends of the
No. 1 to No. n separation columns are connected to the vacuum
tube pipelines through corresponding No. 1 to No. n vacuum
valves 22 respectively; It is a combination of a water ring
pump and a rotary vane pump. The front stage is a water ring
pump and the rear stage is a rotary vane pump with a gas
ballast valve. It can obtain a high degree of vacuum under
water vapor medium conditions.
This embodiment also provides a method for preparing
deuterium-poor water and deuterium-rich water using the above
system, which specifically includes the following steps:
S1: Set the internal temperature of the sealed electric
heating box to above 100°C, turn on the heating ring outside
the separation column to raise the temperature of each
separation column to above 300°C, vacuum to remove the
residual water vapor in the separation column, and then reduce
it to about 100°C;
S2: The natural water in the raw water storage tank is
extracted through the metering pump, and then converted into
water vapor through the vaporizer, and then enters the No. 1
to No. n-1 separation columns;
S3: Turn on the heating ring to raise the temperature of the
No. 1 separation column to above 300°C. The water vapor in the
No. 1 separation column desorbs and the pressure in the column
rises. When it exceeds the opening pressure of the one-way
valve, the water vapor moves backward into the No. 2 column.
This in turn causes the water vapor in column No. 2 to enter
column No. 3 through the one-way valve, and this process
occurs in subsequent separation columns. Finally, all the
water vapor in separation columns No. 1 to No. n-1 enters
separation columns No. 2 to No. n. After the first
rearrangement is completed, the deuterium concentration in the
water vapor gradually decreases along No. 2→N. When there is
no significant change in the pressure in the No. 1 separation
column (that is, after desorption is completed), vacuum the
residual water vapor in the No. 1 column to regenerate it. ,
and turn off the No. 1 column heating ring at the same time;
S4: When the temperature of column 1 drops to about 100°C,
open column 2 and heat it to above 300°C. The water vapor
desorbs and moves backwards driven by the pressure difference.
All the water vapor enters the separation of No. 3 to No. n
and No. 1. column to complete the second rearrangement; after
the desorption of column No. 2 is completed, regenerate column
No. 2 and desorb column No. 3 in the same way to complete the
third rearrangement; subsequent operations on the separation
column are analogous; when the nth After the desorption of the
separation column is completed, the water vapor is rearranged
for the nth time, and the water vapor is again distributed in
the separation columns No. 1 to No. n-1, indicating that the
system has completed this cycle of separation;
S5: Connect the deuterium-rich water storage tank pipeline,
turn on the heating ring to heat the No. 1 separation column,
discharge the deuterium-rich water from the top of the No. 1
separation column and collect it; connect the deuterium-poor
water storage tank pipeline, heat the n-1 separation column
column, drain deuterium-depleted water from the bottom of the
column and collect it.
S6: Sampling and analyzing the deuterium content of the water
vapor in the 2#~(n-2)# separation column. Select a separation
column with a deuterium content close to that of natural
water, and inject raw water vapor from the top. The amount of
injection is equal to that of deuterium-depleted water and
deuterium-depleted water. The extraction amount of
deuterium-rich water is equal; then the separation operation
of the next cycle is carried out.
If the deuterium concentration and extraction amount of
deuterium-rich water and deuterium-poor water separated in one
cycle do not reach the expected values, you can obtain a
larger deuterium concentration gradient by increasing the
number of separation columns or the number of cycles to
achieve the expected separation effect.
Compared with the traditional distillation method and
double-temperature exchange method, it has a simple structure,
cheap fillers, easy control, smaller equipment scale, and
lower construction costs. It can use semi-continuous mode to
directly separate natural water to produce deuterium-poor
water and Deuterium rich water.
The separation system and method of this embodiment are
introduced in detail below with two specific examples.
Example 1: Preparation of deuterium-depleted water in
single cycle mode and deuterium concentration of 80ppm
The core components of the system for separating natural water
to prepare deuterium-poor water and deuterium-rich water of
the present invention are 8 separation columns (No. 1 to No.
8), and the separation columns are numbered (No. 1→No.
2→...→No. 8→No. 1) A closed loop is formed by connecting
end-to-end pipelines in sequence; the system also includes raw
water storage tanks, deuterium-rich water storage tanks,
deuterium-poor water storage tanks, metering pumps,
vaporizers, vacuum pumps, and pipes and valves connecting the
above devices.
The separation column, metering pump, vaporizer and
corresponding connecting pipes and valves are placed in a
sealed electric heating box. The box of the electric heating
box is made of phenolic foam board. There is a dry-burning
electric heating rod at the bottom of the electric heating
box, and a heating temperature control is installed outside
the box. The temperature inside the box is controlled to
105℃~115℃. On the one hand, it ensures that the water vapor
temperature in the system is higher than the boiling point and
will not condense into liquid water; on the other hand,
relatively small temperature fluctuations will not cause the
filler to absorb water. Significant changes in quantity.
The separation column is a stainless steel tube with an outer
diameter of Φ100, a wall thickness of 3mm, and a length of
800mm. The end face of the separation column is welded with a
stainless steel head for sealing; the upper head of the
separation column is connected to the outlet of the one-way
valve, and the lower head is connected to the next stage The
inlet end of the one-way valve of the separation column is
connected with a Φ10 stainless steel ferrule.
The packing in the separation column is 5A molecular sieve
with a particle size of Φ3 to Φ5. The packing amount of a
single column is 3.5kg, and the corresponding water vapor
adsorption capacity is about 500g.
The metering pump is a miniature diaphragm pump that adjusts
the output flow in two dimensions through stroke and
frequency. The stroke is used for coarse adjustment of flow,
and the frequency is used for fine adjustment of flow.
The vaporizer is a Φ10 stainless steel spiral coil. The coil
is placed in a tubular heating furnace. The temperature of the
heating furnace is controlled above 200°C. Liquid water enters
the spiral tube at high temperature and is heated and
vaporized directly into steam. There is no retention of liquid
water. , which facilitates accurate control of raw material
steam flow.
The vacuum pump is a combination of a water ring pump and a
rotary vane pump; the front stage is a water ring pump, and
the rear stage is a rotary vane pump with a gas ballast valve.
The opening pressure difference of the one-way valves (V1 ~
V8) between the separation columns is set to 0.1MPa. When the
pressure in the column exceeds the set value, one-way flow can
occur to the rear separation column.
According to the above system composition, the simulated
moving bed principle is used to separate natural water to
prepare deuterium-poor water and deuterium-rich water. The
specific implementation method is as follows:
S1: Control the internal temperature of the sealed electric
heating box to 105°C ~ 115°C. Turn on the heating ring to
raise the temperature of each separation column to 350°C.
Evacuate the remaining water vapor in the separation column to
make the steady-state vacuum degree better than 10Pa; then
close the heating ring. , lowering the separation column
temperature to 115°C.
S2: Extract the natural water in the raw water storage tank
through a micro metering pump, convert it into water vapor
through the vaporizer, and enter the 1#~7# separation columns;
when the pressure in the 7# column reaches 0.02MPa, it means
that the water vapor adsorption is saturated, corresponding to
The total amount of water vapor adsorption is about 3500g.
S3: Turn on the heating ring to raise the temperature of the
1# separation column to 350°C. The water vapor in the 1#
column desorbs and the pressure in the column rises. When it
exceeds the one-way valve opening pressure by 0.1MPa, the
water vapor moves backward into the 2# column. This in turn
causes the water vapor in the 2# column to enter the 3# column
through the one-way valve, and a similar process occurs in the
subsequent separation columns. Finally, all the water vapor in
the 1# ~ 7# separation columns enters the 2# ~ 8# separation
columns, completing the first Second rearrangement; the
deuterium concentration in water vapor gradually decreases
along 2# → 8#.
When there is no significant change in the pressure in the 1#
separation column, it means that the desorption is completed.
Then vacuum the residual water vapor in the 1# column to
regenerate it, and at the same time turn off the corresponding
heater.
S4: When the temperature of column 1# drops to 115°C, turn on
the heating of column 2#. The water vapor will desorb and move
backward driven by the pressure difference. All the water
vapor will enter the separation columns 3#~8# and 1# to
complete the second time. rearrange.
After the desorption of the 2# column is completed, regenerate
the 2# column and desorb the 3# column in the same manner as
above; subsequent separation column operations can be deduced
by analogy.
When the desorption of the 8# separation column is completed,
the water vapor undergoes the eighth rearrangement, and the
water vapor is again distributed in the 1# to 7# separation
columns, indicating that the system has completed a cycle of
separation; the water vapor forms a significant deuterium
concentration gradient. The deuterium concentration at the top
of the proximal #1 column is the highest, and the deuterium
concentration at the bottom of the distal #7 column is the
lowest.
S5: Extract products and add raw materials based on basic
experimental data and the principle of material conservation:
Connect the deuterium-rich water storage tank pipeline, heat
the No. 1 separation column, and discharge the deuterium-rich
water from the top of the column. The collection volume of
deuterium-rich water is approximately 200g, the deuterium
concentration is about 270ppm; connect the deuterium-depleted
water storage tank pipeline, heat the No. 7 separation column,
and discharge the deuterium-depleted water from the bottom of
the column. The collection amount of deuterium-depleted water
is about 300g, and the deuterium concentration is about 80ppm.
S6: Sampling and analyzing the deuterium content of the water
vapor in No. 2 to No. 6 separation columns shows that the
deuterium content of No. 5 separation column is close to that
of natural water. Inject natural water vapor from the top of
No. 5. The deuterium content of natural water is about 150ppm.
Inject The amount is 500g; based on this method, it will not
have a significant impact on the deuterium concentration
gradient in the water vapor distribution zone.
By repeating the above steps, deuterium-poor water with a
deuterium concentration of about 80 ppm and deuterium-rich
water with a deuterium concentration of 270 ppm can be
prepared in a semi-continuous mode.
Example 2: Preparation of deuterium-depleted water in
double circulation mode with a deuterium concentration of
30ppm
Complete the first cycle separation according to steps S1 to
S4 of Example 1;
Complete the second cycle separation according to steps S3~S4
of Example 1;
Then connect the deuterium-rich water storage tank pipeline,
heat the No. 1 separation column, and discharge the
deuterium-rich water from the top of the column. The
collection volume of deuterium-rich water is about 160g, and
the deuterium concentration is about 410ppm; connect the
deuterium-poor water storage tank pipeline, and heat it. No. 7
separation column discharges deuterium-depleted water from the
bottom of the column. The collection volume of
deuterium-depleted water is about 340g, and the deuterium
concentration is about 30ppm.
Deuterium content sampling and analysis of the water vapor in
No. 2 to No. 6 separation columns showed that the deuterium
content of No. 4 separation column was close to that of
natural water. Natural water vapor was injected from the top
of No. 4, and the injection amount was 500g.
By repeating the above steps, deuterium-poor water with a
deuterium concentration of about 30 ppm and deuterium-rich
water with a deuterium concentration of 410 ppm can be
prepared in a semi-continuous mode.
It can be clearly seen from the above examples that the
separation system of the present invention has a simple
structure, cheap fillers, easy control, smaller equipment
scale, and lower construction costs. When using this system
for separation, the semi-continuous mode can be used to
directly separate natural water. Deuterium-poor water and
deuterium-rich water are produced with high separation
efficiency and good separation effect.
Therapies :
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AND FOODSTUFFS CONTAINING THE SAME Abstract --- FIELD: food processing industry. ^
SUBSTANCE: drinking water with increased content of represents
industrially obtained light water containing at least 997.13
g/kg (or at least 997.36 g/kg, or at least 997.51 g/kg) based on
total water amount, wherein sum amount of 1H2D16O, 1H1D17O,
1H1D18O, and is at most 2.87 g/kg (or at most 2.64 g/kg, or at
most 2.49 g/kg) based on total water amount. Drinking water with
increased content of is useful in production of dairy,
confectionary, bakery, fat-and-oil products, souses, fish and
meat products, pasta, chewing gum, soy products, vinegar, vodka,
brandy, tincture, balsam, liquor, alcohol cocktail, soft drink,
mineralized water, functional products animal feed supplement. ^
EFFECT: water for optimization of isotopic composition in human
body, foodstuffs and beverages of high technological
characteristics.
RO120454 -- GERONTOLOGICAL AND ANTITUMORAL METHOD OF
TREATMENT Abstract --- The invention relates to a
gerontological and antitumoral method of treatment, by means of
deuterium depleted water, which consists in administering light
water, respectively superlight SU1 and SU2 RDW-type, having a
deuterium content of 120 ppm D2O, as beverage or concentrated
beverage, in two successive 30- day stages, separated from each
other by a period of 90 ... 180 days.
RU2270017 -- METHOD FOR TREATMENT OF PATIENTS WITH DIABETES
MELLITUS Abstract --- Treatment involves prescription to
patient light water as drinking water with the total
mineralization 200-500 mg/l, the deuterium content 100 ppm, not
above, and the oxygen-18 content 1800 ppm, not above, on the
background of dietetic therapy and insulin therapy or intake of
hypoglycemic preparations in the daily dose 1000-1500 ml. The
first intake is carried out before eating in the morning in the
dose 200-250 ml and the remaining amount for a day, 30-40 min
before eating or in breaks of eating every day. The curative
course is from 28 to 45 days. Method provides declining the
blood glucose content and to improve metabolic processes. ^
EFFECT: improved treatment method.
RU2287318 -- INDIVIDUAL'S SKIN, HAIR, NAILS, MOUTH CAVITY
CARE MEANS FOR IMPROVING STATE AND APPEARANCE OF THE SAME Abstract --- Individual's skin, hair, nails, mouth
cavity care means for improving state and appearance thereof is
selected from the group consisting of perfume means, cosmetic
means, hygienic means containing light cleared water in the form
of component or base, with content of 1H2 16O in light cleared
water making at least 997.13 g/kg of total amount of H2O, and
acceptable perfume components and/or base, and/or cosmetic
components, and/or base, and/or hygienic components, and/or
base, and/or active substances. Utilization of light water with
increased content of 1H2 16O as best solvent and/or diluent,
and/or carrier of other active components in receipt of said
means is more effective in comparison with similar means
prepared with the use of water with standard content of 1H2 16O.
^ EFFECT: increased efficiency in utilization of said means for
improving state and appearance of individual's skin, hair, nails
and mouth cavity.
JP2005218426 -- METHOD FOR PRODUCING RICE GRUEL,
CREAM AND CURRY OF RETORT PACK USING DEUTERIUM-DEPLETED WATER
(SUPER LIGHT WATER), AND EFFECT THROUGH TAKING THE SAME Abstract --- PROBLEM TO BE SOLVED: To provide a
method for maintaining health by solving the following problem:
usually retort foods such as rice gruel, cream, curry and the
like are produced by using water, but they are impossible to
more surely maintain human health by taking the same. SOLUTION:
The retort pack foods such as rice gruel, cream, curry and the
like are produced by using deuterium-depleted water (super light
water). By taking the retort foods, one's health is possible to
be maintained.
JP2004357678 -- TREATMENT OF CANCER, DIABETES MELLITUS,
LEUKEMIA, APLASTIC ANEMIA AND INSOMNIA, TREATMENT AND
PREVENTION OF SEVERE ACUTE RESPIRATORY SYNDROME (SARS),
REJUVENATION, ACTIVATION OF CELL AND PROMOTION OF INCREASE OF
IMMUNE CELL BY SOY SAUCE PREPARED BY USING DEUTERIUM-ATTRITED
WATER (SUPER LIGHT WATER) AS RAW MATERIAL, AND METHOD FOR
PRODUCING THE SAME Abstract --- PROBLEM TO BE SOLVED: To provide a
method for treating and preventing the following diseases and
performing the rejuvenation, activation of cells and promotion
of the increase of immune cells by solving problems such that,
conventionary, the treatments of cancer, diabetes mellitus,
leukemia, aplastic anemia and insomnia are usually coped with
surgery, radiation treatments, medicinal treatments, and the
like, and in these cases, patients visit directly to hospitals
or clinics and receive treatments, but in the case of SARS,
there is no treating method found. SOLUTION: This soy sauce
produced by using deutrium attrited water (super light water) as
the raw material can be used for the treatment and prevention of
the cancer, diabetes mellitus, aplastic anemia, insomnia and
SARS, rejuvenation, the activation of the cells and promotion of
increase of the immune cells.
JP2004315490 -- THERAPY FOR APLASTIC ANEMIA (MYELODYSPLASTIC
SYNDROME) WITH PHYSIOLOGICAL SALINE SOLUTION OF
DEUTERIUM-REDUCED WATER (SUPER LIGHT WATER) This
invention is a treatment method for aplastic anemia
(myelodysplastic syndrome) by dripping the physiological saline
solution prepared by using the deuterium-reduced water (super
light water) as a solvent into the body of a patient.
JP2004315489 -- TREATMENT FOR PRESBYOPIA AND CATARACT, AND
ACTIVATION OF CRYSTALLINE LENS WITH EYE LOTION OF
DEUTERIUM-REDUCED WATER (SUPER LIGHT WATER) This
invention is to effectively carry out the prevention and
treatment of presbyopia and cataract as well as the activation
of crystalline lenses by using the eye lotion of
deuterium-reduced water (super light water) JP2004315488 -- TREATMENT OF CANCER, DIABETES, LEUKEMIA
AND INSOMNIA AND REJUVENATION, ACTIVATION OF CELL AND
PROMOTION OF IMMUNOCYTE INCREASE BY USING BEER BREWED IN
DEUTERIUM-REDUCED WATER (SUPER LIGHT WATER) AS RAW MATERIAL
This invention
effectively carries out the treatment of cancer, diabetes,
leukemia and isomnia, rejuvenation, activation of cells,
promotion of immunocyte increase by taking the beer that is
brewed in the deuterium-reduced water (super light water) as raw
water. JP2004315487 -- MUSCLAR ENFORCEMENT BY TAKING SPORT DRINK
CONTAINING DEUTERIUM-REDUCED WATER (SUPER LIGHT WATER) AS RAW
MATERIAL, AND METHOD FOR PRODUCING THE SPORT DRINK This invention
is to carry out the muscle enforcement effectively by taking the
sport drink that contains the deuterium-reduced water (super
light water). JP2004315486 -- THERAPY FOR APLASTIC ANEMIA
(MYELODYSPLASTIC SYNDROME) WITH DEUTERIUM-REDUCED WATER (SUPER
LIGHT WATER)
This invention is a
therapeutic method for treating aplastic anemia (myelodysplastic
syndrome) by drinking the deuterium-reduced water
JP2004275658 -- SMALL DAMP TOWEL PREPARED USING DEUTERIUM
DEPLETED WATER (SUPER LIGHT WATER)
JP2004277391 -- TREATMENT OF CANCER, DIABETES, LEUKEMIA
AND INSOMNIA WITH SAKE BREWED USING DEUTERIUM-REDUCED WATER
AND ITS USE FOR REJUVENATION, ACTIVATION OF CELLS, AND
ACCELERATION OF INCREASE OF IMMUNOCYTE, AND PRODUCTION METHOD
THEREOF
The brewing mixture
(Moromi) is prepared by using a mixture of water and the
super-light water that includes ≤ 140 ppm of deuterium, or, as
an activation agent, including ≤ 140 ppm of deuterium in the
form of pharmaceutical products or pharmaceutical solution or of
an aqueous solution acceptable to human, then fermenting the
resultant Moromi to produce Japanese Sake including the super
light water. This Sake is used for treating a variety of
diseases and for enhancing healthiness of people and to treat
cancer, diabetes, leukemia and insomnia and promote
rejuvenation, activate cells and accelerate increase of
immunocyte.
JP2004231627 -- POULTICE UTILIZING DEUTERIUM-ATTRITED
WATER (SUPER LIGHT WATER), METHOD FOR TREATING WRINKLE,
DARKENED SPOT, WART, SKIN CANCER AND RED BLOTCH WITH PACK
This method for
treating the wrinkles, darkened spots, warts, skin cancer and
red blotches is provided by using a poultice containing an
aqueous solution containing deutrium-attrited water (super light
water) or by using a packing containing the same
JP2004217610 -- TREATMENT OF CANCER, DIABETES, LEUKEMIA
AND INSOMNIA, AND PROMOTION OF REJUVENATION, CELL ACTIVATION
AND IMMUNOCYTE PROLIFERATION BY PHYSIOLOGICAL SALINE
COMPRIZING DEUTERIUM-DEPLETED WATER
The treatment of
cancer, diabetes, leukemia and insomnia, and the promotion of
rejuvenation, cell activation and immunocyte proliferation can
effectively be performed by the application of
deuterium-depleted water (super light water) and the
physiological saline containing the deuterium depleted water as
a raw material.
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DEUTERIUM-DIMINISHED WATER (SUPER LIGHT WATER)
This method for
preventing the jet lag is to drink specific deutrium-diminished
water (super light water).
JP2004175775 -- BATH USING DEUTERIUM-DIMINISHED WATER
(SUPER LIGHT WATER) AS BATH WATER AND METHOD FOR PRODUCING
DEUTERIUM-DIMINISHED WATER (SUPER LIGHT WATER)
The method for
necrotizing abnormal cells such as the cancer cells, spots,
wrinkles, of the skin is to take a bath by using the
deutrium-diminished water (super light water) having 25-135 ppm
deutrium water concentration as bath water
JP2004091460 -- METHOD FOR REJUVENATION AND HEALTH
MAINTENANCE BY DEUTRIUM-REDUCED WATER (SUPER LIGHT WATER) AND
METHOD FOR PRODUCING THE WATER
The deutrium-reduced
water contains water and 130-146 ppm deutrium content, or is an
aqueous solution suitable for human, containing 130-146 ppm
deutrium content as an activating agent together with a carrier
or an assistant in the form of a pharmaceutical product or a
medicinal solution form. The method for rejuvenation and health
maintenance by drinking the deutrium-reduced water (super light
water) to reduce the concentration of the deutrium is provided.
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AND PROSTATOMEGALY BY DEUTERIUM-REDUCED WATER (SUPER LIGHT
WATER) JP2004067654 -- METHOD FOR MEDICAL TREATMENT WITH WATER
HAVING DECREASED DEUTERIUM CONTENT (SUPER-LIGHT WATER)